Crystal structure of 3-methyl-2,6-bis­(4-methyl-1,3-thia­zol-5-yl)piperidin-4-one

In the title compound, C(14)H(17)N(3)OS(2), the central piperidinone ring adopts a chair conformation and the thia­zole rings are inclined to its mean plane by 80.16 (12) and 67.15 (12)°. The O atom and methyl group C atom deviate significantly from the mean plane of the central piperidinone ring, b...

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Detalles Bibliográficos
Autores principales: Manimaran, A., Sethusankar, K., Ganesan, S., Ananthan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186075/
https://www.ncbi.nlm.nih.gov/pubmed/25309222
http://dx.doi.org/10.1107/S1600536814018856
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author Manimaran, A.
Sethusankar, K.
Ganesan, S.
Ananthan, S.
author_facet Manimaran, A.
Sethusankar, K.
Ganesan, S.
Ananthan, S.
author_sort Manimaran, A.
collection PubMed
description In the title compound, C(14)H(17)N(3)OS(2), the central piperidinone ring adopts a chair conformation and the thia­zole rings are inclined to its mean plane by 80.16 (12) and 67.15 (12)°. The O atom and methyl group C atom deviate significantly from the mean plane of the central piperidinone ring, by 0.8138 (2) and 0.3175 (2) Å, respectively. The dihedral angle between the thia­zole rings is 51.88 (13)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming zigzag C(10) chains running parallel to [001].
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spelling pubmed-41860752014-10-12 Crystal structure of 3-methyl-2,6-bis­(4-methyl-1,3-thia­zol-5-yl)piperidin-4-one Manimaran, A. Sethusankar, K. Ganesan, S. Ananthan, S. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(14)H(17)N(3)OS(2), the central piperidinone ring adopts a chair conformation and the thia­zole rings are inclined to its mean plane by 80.16 (12) and 67.15 (12)°. The O atom and methyl group C atom deviate significantly from the mean plane of the central piperidinone ring, by 0.8138 (2) and 0.3175 (2) Å, respectively. The dihedral angle between the thia­zole rings is 51.88 (13)°. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming zigzag C(10) chains running parallel to [001]. International Union of Crystallography 2014-08-30 /pmc/articles/PMC4186075/ /pubmed/25309222 http://dx.doi.org/10.1107/S1600536814018856 Text en © Manimaran et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Manimaran, A.
Sethusankar, K.
Ganesan, S.
Ananthan, S.
Crystal structure of 3-methyl-2,6-bis­(4-methyl-1,3-thia­zol-5-yl)piperidin-4-one
title Crystal structure of 3-methyl-2,6-bis­(4-methyl-1,3-thia­zol-5-yl)piperidin-4-one
title_full Crystal structure of 3-methyl-2,6-bis­(4-methyl-1,3-thia­zol-5-yl)piperidin-4-one
title_fullStr Crystal structure of 3-methyl-2,6-bis­(4-methyl-1,3-thia­zol-5-yl)piperidin-4-one
title_full_unstemmed Crystal structure of 3-methyl-2,6-bis­(4-methyl-1,3-thia­zol-5-yl)piperidin-4-one
title_short Crystal structure of 3-methyl-2,6-bis­(4-methyl-1,3-thia­zol-5-yl)piperidin-4-one
title_sort crystal structure of 3-methyl-2,6-bis­(4-methyl-1,3-thia­zol-5-yl)piperidin-4-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186075/
https://www.ncbi.nlm.nih.gov/pubmed/25309222
http://dx.doi.org/10.1107/S1600536814018856
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