Crystal structure of 1-ferrocenyl-2-(4-methyl­benzo­yl)spiro­[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline]

In the title compound, [Fe(C(5)H(5))(C(34)H(28)N(3)O)], the four-fused-rings system of the 11H-indeno­[1,2-b]quinoxaline unit is approximately planar [maximum deviation = 0.167 (4) Å] and forms a dihedral angle of 37.25 (6)° with the plane of the benzene ring of the methyl­benzoyl group. Both pyrrol...

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Autores principales: Chandralekha, Kuppan, Gavaskar, Deivasigamani, Sureshbabu, Adukamparai Rajukrishnan, Lakshmi, Srinivasakannan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186081/
https://www.ncbi.nlm.nih.gov/pubmed/25309158
http://dx.doi.org/10.1107/S1600536814017644
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author Chandralekha, Kuppan
Gavaskar, Deivasigamani
Sureshbabu, Adukamparai Rajukrishnan
Lakshmi, Srinivasakannan
author_facet Chandralekha, Kuppan
Gavaskar, Deivasigamani
Sureshbabu, Adukamparai Rajukrishnan
Lakshmi, Srinivasakannan
author_sort Chandralekha, Kuppan
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(34)H(28)N(3)O)], the four-fused-rings system of the 11H-indeno­[1,2-b]quinoxaline unit is approximately planar [maximum deviation = 0.167 (4) Å] and forms a dihedral angle of 37.25 (6)° with the plane of the benzene ring of the methyl­benzoyl group. Both pyrrolidine rings adopt a twist conformation. An intra­molecular C—H⋯O hydrogen bond is observed. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and weak C—H⋯π inter­actions, forming double chains extending parallel to the c axis.
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spelling pubmed-41860812014-10-12 Crystal structure of 1-ferrocenyl-2-(4-methyl­benzo­yl)spiro­[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline] Chandralekha, Kuppan Gavaskar, Deivasigamani Sureshbabu, Adukamparai Rajukrishnan Lakshmi, Srinivasakannan Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Fe(C(5)H(5))(C(34)H(28)N(3)O)], the four-fused-rings system of the 11H-indeno­[1,2-b]quinoxaline unit is approximately planar [maximum deviation = 0.167 (4) Å] and forms a dihedral angle of 37.25 (6)° with the plane of the benzene ring of the methyl­benzoyl group. Both pyrrolidine rings adopt a twist conformation. An intra­molecular C—H⋯O hydrogen bond is observed. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and weak C—H⋯π inter­actions, forming double chains extending parallel to the c axis. International Union of Crystallography 2014-08-09 /pmc/articles/PMC4186081/ /pubmed/25309158 http://dx.doi.org/10.1107/S1600536814017644 Text en © Chandralekha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Chandralekha, Kuppan
Gavaskar, Deivasigamani
Sureshbabu, Adukamparai Rajukrishnan
Lakshmi, Srinivasakannan
Crystal structure of 1-ferrocenyl-2-(4-methyl­benzo­yl)spiro­[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline]
title Crystal structure of 1-ferrocenyl-2-(4-methyl­benzo­yl)spiro­[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline]
title_full Crystal structure of 1-ferrocenyl-2-(4-methyl­benzo­yl)spiro­[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline]
title_fullStr Crystal structure of 1-ferrocenyl-2-(4-methyl­benzo­yl)spiro­[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline]
title_full_unstemmed Crystal structure of 1-ferrocenyl-2-(4-methyl­benzo­yl)spiro­[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline]
title_short Crystal structure of 1-ferrocenyl-2-(4-methyl­benzo­yl)spiro­[11H-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline]
title_sort crystal structure of 1-ferrocenyl-2-(4-methyl­benzo­yl)spiro­[11h-pyrrolidizine-3,11′-indeno[1,2-b]quinoxaline]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186081/
https://www.ncbi.nlm.nih.gov/pubmed/25309158
http://dx.doi.org/10.1107/S1600536814017644
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