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Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]
The title compound, [Co(C(15)H(11)N(3))(H(2)O){Pt(CN)(4)}](n), is a one-dimensional coordination polymer formed under hydrothermal reaction conditions. The Co(II) site has sixfold coordination with a distorted octahedral geometry, while the Pt(II) ion is coordinated by four cyanide groups in an al...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186089/ https://www.ncbi.nlm.nih.gov/pubmed/25309181 http://dx.doi.org/10.1107/S1600536814017425 |
Sumario: | The title compound, [Co(C(15)H(11)N(3))(H(2)O){Pt(CN)(4)}](n), is a one-dimensional coordination polymer formed under hydrothermal reaction conditions. The Co(II) site has sixfold coordination with a distorted octahedral geometry, while the Pt(II) ion is coordinated by four cyanide groups in an almost regular square-planar geometry. The compound contains twofold rotation symmetry about its Co(II) ion, the water molecule and the terpyridine ligand, and the Pt(II) atom resides on an inversion center. trans-Bridging by the tetracyanidoplatinate(II) anions links the Co(II) cations, forming chains parallel to [-101]. Additionally, each Co(II) atom is coordinated by one water molecule and one tridentate 2,2′:6′,2′′-terpyridine ligand. O—H⋯N hydrogen-bonding interactions are found between adjacent chains and help to consolidate the crystal packing. In addition, relatively weak π–π stacking interactions exist between the terpyridine ligands of adjacent chains [interplanar distance = 3.464 (7) Å]. No Pt⋯Pt interactions are observed in the structure. |
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