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Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]
The title compound, [Co(C(15)H(11)N(3))(H(2)O){Pt(CN)(4)}](n), is a one-dimensional coordination polymer formed under hydrothermal reaction conditions. The Co(II) site has sixfold coordination with a distorted octahedral geometry, while the Pt(II) ion is coordinated by four cyanide groups in an al...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186089/ https://www.ncbi.nlm.nih.gov/pubmed/25309181 http://dx.doi.org/10.1107/S1600536814017425 |
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author | White, Frankie Sykora, Richard E. |
author_facet | White, Frankie Sykora, Richard E. |
author_sort | White, Frankie |
collection | PubMed |
description | The title compound, [Co(C(15)H(11)N(3))(H(2)O){Pt(CN)(4)}](n), is a one-dimensional coordination polymer formed under hydrothermal reaction conditions. The Co(II) site has sixfold coordination with a distorted octahedral geometry, while the Pt(II) ion is coordinated by four cyanide groups in an almost regular square-planar geometry. The compound contains twofold rotation symmetry about its Co(II) ion, the water molecule and the terpyridine ligand, and the Pt(II) atom resides on an inversion center. trans-Bridging by the tetracyanidoplatinate(II) anions links the Co(II) cations, forming chains parallel to [-101]. Additionally, each Co(II) atom is coordinated by one water molecule and one tridentate 2,2′:6′,2′′-terpyridine ligand. O—H⋯N hydrogen-bonding interactions are found between adjacent chains and help to consolidate the crystal packing. In addition, relatively weak π–π stacking interactions exist between the terpyridine ligands of adjacent chains [interplanar distance = 3.464 (7) Å]. No Pt⋯Pt interactions are observed in the structure. |
format | Online Article Text |
id | pubmed-4186089 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41860892014-10-12 Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N] White, Frankie Sykora, Richard E. Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, [Co(C(15)H(11)N(3))(H(2)O){Pt(CN)(4)}](n), is a one-dimensional coordination polymer formed under hydrothermal reaction conditions. The Co(II) site has sixfold coordination with a distorted octahedral geometry, while the Pt(II) ion is coordinated by four cyanide groups in an almost regular square-planar geometry. The compound contains twofold rotation symmetry about its Co(II) ion, the water molecule and the terpyridine ligand, and the Pt(II) atom resides on an inversion center. trans-Bridging by the tetracyanidoplatinate(II) anions links the Co(II) cations, forming chains parallel to [-101]. Additionally, each Co(II) atom is coordinated by one water molecule and one tridentate 2,2′:6′,2′′-terpyridine ligand. O—H⋯N hydrogen-bonding interactions are found between adjacent chains and help to consolidate the crystal packing. In addition, relatively weak π–π stacking interactions exist between the terpyridine ligands of adjacent chains [interplanar distance = 3.464 (7) Å]. No Pt⋯Pt interactions are observed in the structure. International Union of Crystallography 2014-08-06 /pmc/articles/PMC4186089/ /pubmed/25309181 http://dx.doi.org/10.1107/S1600536814017425 Text en © White and Sykora 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports White, Frankie Sykora, Richard E. Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N] |
title | Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2)
N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2)
C:N] |
title_full | Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2)
N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2)
C:N] |
title_fullStr | Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2)
N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2)
C:N] |
title_full_unstemmed | Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2)
N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2)
C:N] |
title_short | Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3)
N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2)
N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2)
C:N] |
title_sort | crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3)
n,n′,n′′)cobalt(ii)]-μ-cyanido-κ(2)
n:c-[dicyanidoplatinum(ii)]-μ-cyanido-κ(2)
c:n] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186089/ https://www.ncbi.nlm.nih.gov/pubmed/25309181 http://dx.doi.org/10.1107/S1600536814017425 |
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