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Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]

The title compound, [Co(C(15)H(11)N(3))(H(2)O){Pt(CN)(4)}](n), is a one-dimensional coordination polymer formed under hydro­thermal reaction conditions. The Co(II) site has sixfold coordination with a distorted octa­hedral geometry, while the Pt(II) ion is coordinated by four cyanide groups in an al...

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Autores principales: White, Frankie, Sykora, Richard E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186089/
https://www.ncbi.nlm.nih.gov/pubmed/25309181
http://dx.doi.org/10.1107/S1600536814017425
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author White, Frankie
Sykora, Richard E.
author_facet White, Frankie
Sykora, Richard E.
author_sort White, Frankie
collection PubMed
description The title compound, [Co(C(15)H(11)N(3))(H(2)O){Pt(CN)(4)}](n), is a one-dimensional coordination polymer formed under hydro­thermal reaction conditions. The Co(II) site has sixfold coordination with a distorted octa­hedral geometry, while the Pt(II) ion is coordinated by four cyanide groups in an almost regular square-planar geometry. The compound contains twofold rotation symmetry about its Co(II) ion, the water molecule and the terpyridine ligand, and the Pt(II) atom resides on an inversion center. trans-Bridging by the tetra­cyanidoplatinate(II) anions links the Co(II) cations, forming chains parallel to [-101]. Additionally, each Co(II) atom is coordin­ated by one water mol­ecule and one tridentate 2,2′:6′,2′′-terpyridine ligand. O—H⋯N hydrogen-bonding inter­actions are found between adjacent chains and help to consolidate the crystal packing. In addition, relatively weak π–π stacking inter­actions exist between the terpyridine ligands of adjacent chains [inter­planar distance = 3.464 (7) Å]. No Pt⋯Pt inter­actions are observed in the structure.
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spelling pubmed-41860892014-10-12 Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N] White, Frankie Sykora, Richard E. Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, [Co(C(15)H(11)N(3))(H(2)O){Pt(CN)(4)}](n), is a one-dimensional coordination polymer formed under hydro­thermal reaction conditions. The Co(II) site has sixfold coordination with a distorted octa­hedral geometry, while the Pt(II) ion is coordinated by four cyanide groups in an almost regular square-planar geometry. The compound contains twofold rotation symmetry about its Co(II) ion, the water molecule and the terpyridine ligand, and the Pt(II) atom resides on an inversion center. trans-Bridging by the tetra­cyanidoplatinate(II) anions links the Co(II) cations, forming chains parallel to [-101]. Additionally, each Co(II) atom is coordin­ated by one water mol­ecule and one tridentate 2,2′:6′,2′′-terpyridine ligand. O—H⋯N hydrogen-bonding inter­actions are found between adjacent chains and help to consolidate the crystal packing. In addition, relatively weak π–π stacking inter­actions exist between the terpyridine ligands of adjacent chains [inter­planar distance = 3.464 (7) Å]. No Pt⋯Pt inter­actions are observed in the structure. International Union of Crystallography 2014-08-06 /pmc/articles/PMC4186089/ /pubmed/25309181 http://dx.doi.org/10.1107/S1600536814017425 Text en © White and Sykora 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
White, Frankie
Sykora, Richard E.
Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]
title Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]
title_full Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]
title_fullStr Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]
title_full_unstemmed Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]
title_short Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]
title_sort crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)cobalt(ii)]-μ-cyanido-κ(2) n:c-[dicyanidoplatinum(ii)]-μ-cyanido-κ(2) c:n]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186089/
https://www.ncbi.nlm.nih.gov/pubmed/25309181
http://dx.doi.org/10.1107/S1600536814017425
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