Crystal structure of (benzene­carbo­thio­amide-κS)chloridobis­(tri­phenyl­phosphane-κP)silver(I)

In the mononuclear mixed-ligand title complex, [AgCl(C(7)H(7)NS)(C(18)H(15)P)(2)], the Ag(I) ion is four coordinated by one S atom of a benzene­carbo­thio­amide ligand, two P atoms of two tri­phenyl­phosphane ligands and one chloride ion, displaying a distorted tetra­hedral coordination geometry. In...

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Detalles Bibliográficos
Autores principales: Ruangwut, Wattana, Pakawatchai, Chaveng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186092/
https://www.ncbi.nlm.nih.gov/pubmed/25309175
http://dx.doi.org/10.1107/S1600536814015992
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author Ruangwut, Wattana
Pakawatchai, Chaveng
author_facet Ruangwut, Wattana
Pakawatchai, Chaveng
author_sort Ruangwut, Wattana
collection PubMed
description In the mononuclear mixed-ligand title complex, [AgCl(C(7)H(7)NS)(C(18)H(15)P)(2)], the Ag(I) ion is four coordinated by one S atom of a benzene­carbo­thio­amide ligand, two P atoms of two tri­phenyl­phosphane ligands and one chloride ion, displaying a distorted tetra­hedral coordination geometry. In the crystal, pairs of N—H⋯Cl hydrogen bonds form inversion dimers. An intra­molecular N—H⋯Cl hydrogen bond is also observed.
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spelling pubmed-41860922014-10-12 Crystal structure of (benzene­carbo­thio­amide-κS)chloridobis­(tri­phenyl­phosphane-κP)silver(I) Ruangwut, Wattana Pakawatchai, Chaveng Acta Crystallogr Sect E Struct Rep Online Data Reports In the mononuclear mixed-ligand title complex, [AgCl(C(7)H(7)NS)(C(18)H(15)P)(2)], the Ag(I) ion is four coordinated by one S atom of a benzene­carbo­thio­amide ligand, two P atoms of two tri­phenyl­phosphane ligands and one chloride ion, displaying a distorted tetra­hedral coordination geometry. In the crystal, pairs of N—H⋯Cl hydrogen bonds form inversion dimers. An intra­molecular N—H⋯Cl hydrogen bond is also observed. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186092/ /pubmed/25309175 http://dx.doi.org/10.1107/S1600536814015992 Text en © Ruangwut and Pakawatchai 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ruangwut, Wattana
Pakawatchai, Chaveng
Crystal structure of (benzene­carbo­thio­amide-κS)chloridobis­(tri­phenyl­phosphane-κP)silver(I)
title Crystal structure of (benzene­carbo­thio­amide-κS)chloridobis­(tri­phenyl­phosphane-κP)silver(I)
title_full Crystal structure of (benzene­carbo­thio­amide-κS)chloridobis­(tri­phenyl­phosphane-κP)silver(I)
title_fullStr Crystal structure of (benzene­carbo­thio­amide-κS)chloridobis­(tri­phenyl­phosphane-κP)silver(I)
title_full_unstemmed Crystal structure of (benzene­carbo­thio­amide-κS)chloridobis­(tri­phenyl­phosphane-κP)silver(I)
title_short Crystal structure of (benzene­carbo­thio­amide-κS)chloridobis­(tri­phenyl­phosphane-κP)silver(I)
title_sort crystal structure of (benzene­carbo­thio­amide-κs)chloridobis­(tri­phenyl­phosphane-κp)silver(i)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186092/
https://www.ncbi.nlm.nih.gov/pubmed/25309175
http://dx.doi.org/10.1107/S1600536814015992
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