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Crystal structure of bis{μ-4-methyl-N′-[3-(oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato}bis[(dimethyl sulfoxide-κO)copper(II)]
In the title compound, [Cu(2)(C(11)H(13)N(3)O(3)S)(2)(C(2)H(6)OS)(2)], the Cu(II) cation is N,N′,O-chelated by a deprotonated hydroxyimino-tosylhydrazone ligand and coordinated by a dimethyl sulfoxide molecule. One O atom from the adjacent hydroxyimino-tosylhydrazone ligand bridges the Cu(II)...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186093/ https://www.ncbi.nlm.nih.gov/pubmed/25309178 http://dx.doi.org/10.1107/S1600536814016651 |
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author | Siqueira, Diego Pereira Siqueira, Maria Carolina Bulhosa Gervini, Vanessa Carratu Bresolin, Leandro de Oliveira, Adriano Bof |
author_facet | Siqueira, Diego Pereira Siqueira, Maria Carolina Bulhosa Gervini, Vanessa Carratu Bresolin, Leandro de Oliveira, Adriano Bof |
author_sort | Siqueira, Diego Pereira |
collection | PubMed |
description | In the title compound, [Cu(2)(C(11)H(13)N(3)O(3)S)(2)(C(2)H(6)OS)(2)], the Cu(II) cation is N,N′,O-chelated by a deprotonated hydroxyimino-tosylhydrazone ligand and coordinated by a dimethyl sulfoxide molecule. One O atom from the adjacent hydroxyimino-tosylhydrazone ligand bridges the Cu(II) cation, forming the centrosymmetric dimeric complex. The cation is in an overall distorted N(2)O(3) square-pyramidal coordination environment. The methylbenzene ring is twisted with respect to the hydrazine fragment, with a dihedral angle of 89.54 (9)° between the planes. An intramolecular C—H⋯O hydrogen bond occurs. In the crystal, molecules are linked by weak C—H⋯O and C—H⋯S interactions. Weak π–π stacking is also observed between parallel benzene rings of adjacent molecules, the centroid–centroid distance being 3.9592 (17) Å. |
format | Online Article Text |
id | pubmed-4186093 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41860932014-10-12 Crystal structure of bis{μ-4-methyl-N′-[3-(oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato}bis[(dimethyl sulfoxide-κO)copper(II)] Siqueira, Diego Pereira Siqueira, Maria Carolina Bulhosa Gervini, Vanessa Carratu Bresolin, Leandro de Oliveira, Adriano Bof Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, [Cu(2)(C(11)H(13)N(3)O(3)S)(2)(C(2)H(6)OS)(2)], the Cu(II) cation is N,N′,O-chelated by a deprotonated hydroxyimino-tosylhydrazone ligand and coordinated by a dimethyl sulfoxide molecule. One O atom from the adjacent hydroxyimino-tosylhydrazone ligand bridges the Cu(II) cation, forming the centrosymmetric dimeric complex. The cation is in an overall distorted N(2)O(3) square-pyramidal coordination environment. The methylbenzene ring is twisted with respect to the hydrazine fragment, with a dihedral angle of 89.54 (9)° between the planes. An intramolecular C—H⋯O hydrogen bond occurs. In the crystal, molecules are linked by weak C—H⋯O and C—H⋯S interactions. Weak π–π stacking is also observed between parallel benzene rings of adjacent molecules, the centroid–centroid distance being 3.9592 (17) Å. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186093/ /pubmed/25309178 http://dx.doi.org/10.1107/S1600536814016651 Text en © Siqueira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Siqueira, Diego Pereira Siqueira, Maria Carolina Bulhosa Gervini, Vanessa Carratu Bresolin, Leandro de Oliveira, Adriano Bof Crystal structure of bis{μ-4-methyl-N′-[3-(oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato}bis[(dimethyl sulfoxide-κO)copper(II)] |
title | Crystal structure of bis{μ-4-methyl-N′-[3-(oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato}bis[(dimethyl sulfoxide-κO)copper(II)] |
title_full | Crystal structure of bis{μ-4-methyl-N′-[3-(oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato}bis[(dimethyl sulfoxide-κO)copper(II)] |
title_fullStr | Crystal structure of bis{μ-4-methyl-N′-[3-(oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato}bis[(dimethyl sulfoxide-κO)copper(II)] |
title_full_unstemmed | Crystal structure of bis{μ-4-methyl-N′-[3-(oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato}bis[(dimethyl sulfoxide-κO)copper(II)] |
title_short | Crystal structure of bis{μ-4-methyl-N′-[3-(oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato}bis[(dimethyl sulfoxide-κO)copper(II)] |
title_sort | crystal structure of bis{μ-4-methyl-n′-[3-(oxidoimino)butan-2-ylidene]benzenesulfonohydrazidato}bis[(dimethyl sulfoxide-κo)copper(ii)] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186093/ https://www.ncbi.nlm.nih.gov/pubmed/25309178 http://dx.doi.org/10.1107/S1600536814016651 |
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