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Crystal structure of bis­{μ-4-methyl-N′-[3-(oxido­imino)­butan-2-yl­idene]benzene­sulfono­hydrazidato}bis­[(dimethyl sulfoxide-κO)copper(II)]

In the title compound, [Cu(2)(C(11)H(13)N(3)O(3)S)(2)(C(2)H(6)OS)(2)], the Cu(II) cation is N,N′,O-chelated by a deprotonated hy­droxy­imino-tosyl­hydrazone ligand and coordinated by a dimethyl sulfoxide mol­ecule. One O atom from the adjacent hy­droxy­imino-tosyl­hydrazone ligand bridges the Cu(II)...

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Autores principales: Siqueira, Diego Pereira, Siqueira, Maria Carolina Bulhosa, Gervini, Vanessa Carratu, Bresolin, Leandro, de Oliveira, Adriano Bof
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186093/
https://www.ncbi.nlm.nih.gov/pubmed/25309178
http://dx.doi.org/10.1107/S1600536814016651
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author Siqueira, Diego Pereira
Siqueira, Maria Carolina Bulhosa
Gervini, Vanessa Carratu
Bresolin, Leandro
de Oliveira, Adriano Bof
author_facet Siqueira, Diego Pereira
Siqueira, Maria Carolina Bulhosa
Gervini, Vanessa Carratu
Bresolin, Leandro
de Oliveira, Adriano Bof
author_sort Siqueira, Diego Pereira
collection PubMed
description In the title compound, [Cu(2)(C(11)H(13)N(3)O(3)S)(2)(C(2)H(6)OS)(2)], the Cu(II) cation is N,N′,O-chelated by a deprotonated hy­droxy­imino-tosyl­hydrazone ligand and coordinated by a dimethyl sulfoxide mol­ecule. One O atom from the adjacent hy­droxy­imino-tosyl­hydrazone ligand bridges the Cu(II) cation, forming the centrosymmetric dimeric complex. The cation is in an overall distorted N(2)O(3) square-pyramidal coordination environment. The methyl­benzene ring is twisted with respect to the hydrazine fragment, with a dihedral angle of 89.54 (9)° between the planes. An intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯S inter­actions. Weak π–π stacking is also observed between parallel benzene rings of adjacent mol­ecules, the centroid–centroid distance being 3.9592 (17) Å.
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spelling pubmed-41860932014-10-12 Crystal structure of bis­{μ-4-methyl-N′-[3-(oxido­imino)­butan-2-yl­idene]benzene­sulfono­hydrazidato}bis­[(dimethyl sulfoxide-κO)copper(II)] Siqueira, Diego Pereira Siqueira, Maria Carolina Bulhosa Gervini, Vanessa Carratu Bresolin, Leandro de Oliveira, Adriano Bof Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, [Cu(2)(C(11)H(13)N(3)O(3)S)(2)(C(2)H(6)OS)(2)], the Cu(II) cation is N,N′,O-chelated by a deprotonated hy­droxy­imino-tosyl­hydrazone ligand and coordinated by a dimethyl sulfoxide mol­ecule. One O atom from the adjacent hy­droxy­imino-tosyl­hydrazone ligand bridges the Cu(II) cation, forming the centrosymmetric dimeric complex. The cation is in an overall distorted N(2)O(3) square-pyramidal coordination environment. The methyl­benzene ring is twisted with respect to the hydrazine fragment, with a dihedral angle of 89.54 (9)° between the planes. An intra­molecular C—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯S inter­actions. Weak π–π stacking is also observed between parallel benzene rings of adjacent mol­ecules, the centroid–centroid distance being 3.9592 (17) Å. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186093/ /pubmed/25309178 http://dx.doi.org/10.1107/S1600536814016651 Text en © Siqueira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Siqueira, Diego Pereira
Siqueira, Maria Carolina Bulhosa
Gervini, Vanessa Carratu
Bresolin, Leandro
de Oliveira, Adriano Bof
Crystal structure of bis­{μ-4-methyl-N′-[3-(oxido­imino)­butan-2-yl­idene]benzene­sulfono­hydrazidato}bis­[(dimethyl sulfoxide-κO)copper(II)]
title Crystal structure of bis­{μ-4-methyl-N′-[3-(oxido­imino)­butan-2-yl­idene]benzene­sulfono­hydrazidato}bis­[(dimethyl sulfoxide-κO)copper(II)]
title_full Crystal structure of bis­{μ-4-methyl-N′-[3-(oxido­imino)­butan-2-yl­idene]benzene­sulfono­hydrazidato}bis­[(dimethyl sulfoxide-κO)copper(II)]
title_fullStr Crystal structure of bis­{μ-4-methyl-N′-[3-(oxido­imino)­butan-2-yl­idene]benzene­sulfono­hydrazidato}bis­[(dimethyl sulfoxide-κO)copper(II)]
title_full_unstemmed Crystal structure of bis­{μ-4-methyl-N′-[3-(oxido­imino)­butan-2-yl­idene]benzene­sulfono­hydrazidato}bis­[(dimethyl sulfoxide-κO)copper(II)]
title_short Crystal structure of bis­{μ-4-methyl-N′-[3-(oxido­imino)­butan-2-yl­idene]benzene­sulfono­hydrazidato}bis­[(dimethyl sulfoxide-κO)copper(II)]
title_sort crystal structure of bis­{μ-4-methyl-n′-[3-(oxido­imino)­butan-2-yl­idene]benzene­sulfono­hydrazidato}bis­[(dimethyl sulfoxide-κo)copper(ii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186093/
https://www.ncbi.nlm.nih.gov/pubmed/25309178
http://dx.doi.org/10.1107/S1600536814016651
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