Crystal structure of 1-meth­oxy-2,2,2-tris­(pyrazol-1-yl)ethane

The title compound, C(12)H(14)N(6)O, consists of three pyrazole rings bound via nitro­gen to the distal ethane carbon of meth­oxy ethane. The dihedral angles between the three pyrazole rings are 67.62 (14), 73.74 (14), and 78.92 (12)°. In the crystal, mol­ecules are linked by bifurcated C—H,H⋯N hydr...

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Detalles Bibliográficos
Autores principales: Lyubartseva, Ganna, Parkin, Sean, Coleman, Morgan D., Mallik, Uma Prasad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186097/
https://www.ncbi.nlm.nih.gov/pubmed/25309218
http://dx.doi.org/10.1107/S1600536814018789
Descripción
Sumario:The title compound, C(12)H(14)N(6)O, consists of three pyrazole rings bound via nitro­gen to the distal ethane carbon of meth­oxy ethane. The dihedral angles between the three pyrazole rings are 67.62 (14), 73.74 (14), and 78.92 (12)°. In the crystal, mol­ecules are linked by bifurcated C—H,H⋯N hydrogen bonds, forming double-stranded chains along [001]. The chains are linked via C—H⋯O hydrogen bonds, forming a three-dimensional framework structure. The crystal was refined as a perfect (0.5:0.5) inversion twin.

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