Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methyl­cyclo­hexyl­idene]hydrazine-1-carbo­thio­amide

The title compound, C(11)H(21)N(3)S, consists of a menthone moiety attached to an extended thio­semicarbazone group with the N—N—C—N torsion angle being 11.92 (16)°. The cyclo­hexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, mol­ecules are linked via...

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Autores principales: de Oliveira, Adriano Bof, Beck, Johannes, Daniels, Jörg, de Farias, Renan Lira, de Godoy Netto, Adelino Vieira
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186105/
https://www.ncbi.nlm.nih.gov/pubmed/25309244
http://dx.doi.org/10.1107/S1600536814015980
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author de Oliveira, Adriano Bof
Beck, Johannes
Daniels, Jörg
de Farias, Renan Lira
de Godoy Netto, Adelino Vieira
author_facet de Oliveira, Adriano Bof
Beck, Johannes
Daniels, Jörg
de Farias, Renan Lira
de Godoy Netto, Adelino Vieira
author_sort de Oliveira, Adriano Bof
collection PubMed
description The title compound, C(11)H(21)N(3)S, consists of a menthone moiety attached to an extended thio­semicarbazone group with the N—N—C—N torsion angle being 11.92 (16)°. The cyclo­hexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, mol­ecules are linked via pairs of N—H⋯S hydrogen bonds, forming chains along the a axis. The absolute structure could be assigned with reference to the starting material, i.e. enanti­opure (−)-menthone [Flack parameter = 0.05 (5)].
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spelling pubmed-41861052014-10-12 Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methyl­cyclo­hexyl­idene]hydrazine-1-carbo­thio­amide de Oliveira, Adriano Bof Beck, Johannes Daniels, Jörg de Farias, Renan Lira de Godoy Netto, Adelino Vieira Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, C(11)H(21)N(3)S, consists of a menthone moiety attached to an extended thio­semicarbazone group with the N—N—C—N torsion angle being 11.92 (16)°. The cyclo­hexane ring has a chair conformation and the conformation about the C=N bond is E. In the crystal, mol­ecules are linked via pairs of N—H⋯S hydrogen bonds, forming chains along the a axis. The absolute structure could be assigned with reference to the starting material, i.e. enanti­opure (−)-menthone [Flack parameter = 0.05 (5)]. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186105/ /pubmed/25309244 http://dx.doi.org/10.1107/S1600536814015980 Text en © Oliveira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
de Oliveira, Adriano Bof
Beck, Johannes
Daniels, Jörg
de Farias, Renan Lira
de Godoy Netto, Adelino Vieira
Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methyl­cyclo­hexyl­idene]hydrazine-1-carbo­thio­amide
title Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methyl­cyclo­hexyl­idene]hydrazine-1-carbo­thio­amide
title_full Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methyl­cyclo­hexyl­idene]hydrazine-1-carbo­thio­amide
title_fullStr Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methyl­cyclo­hexyl­idene]hydrazine-1-carbo­thio­amide
title_full_unstemmed Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methyl­cyclo­hexyl­idene]hydrazine-1-carbo­thio­amide
title_short Crystal structure of (E)-2-[(2S,5R)-2-isopropyl-5-methyl­cyclo­hexyl­idene]hydrazine-1-carbo­thio­amide
title_sort crystal structure of (e)-2-[(2s,5r)-2-isopropyl-5-methyl­cyclo­hexyl­idene]hydrazine-1-carbo­thio­amide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186105/
https://www.ncbi.nlm.nih.gov/pubmed/25309244
http://dx.doi.org/10.1107/S1600536814015980
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