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Crystal structure of [propane-1,3-diylbis(piperidine-4,1-di­yl)]bis­[(pyridin-4-yl)methanone]–4,4′-oxydi­benzoic acid (1/1)

In the title co-crystal, C(25)H(32)N(4)O(2)·C(14)H(10)O(5), mol­ecules are connected into supra­molecular chains aligned along [102] by O—H⋯N hydrogen bonding. These aggregate into supra­molecular layers oriented parallel to (20-1) by C—H⋯O inter­actions. These layers then stack in an ABAB pattern a...

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Detalles Bibliográficos
Autores principales: Low, Emily M., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186108/
https://www.ncbi.nlm.nih.gov/pubmed/25309203
http://dx.doi.org/10.1107/S160053681401811X
Descripción
Sumario:In the title co-crystal, C(25)H(32)N(4)O(2)·C(14)H(10)O(5), mol­ecules are connected into supra­molecular chains aligned along [102] by O—H⋯N hydrogen bonding. These aggregate into supra­molecular layers oriented parallel to (20-1) by C—H⋯O inter­actions. These layers then stack in an ABAB pattern along the c crystal direction to give the full three-dimensional crystal structure. The central chain in the dipyridylamide has an anti–anti conformation. The dihedral angle between the aromatic ring planes is 29.96 (3)°. Disorder is noted in some of the residues in the structure and this is manifested in two coplanar dispositions of one statistically disordered carb­oxy­lic acid group.