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Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1)
In the title co-crystal, C(25)H(32)N(4)O(2)·C(14)H(10)O(5), molecules are connected into supramolecular chains aligned along [102] by O—H⋯N hydrogen bonding. These aggregate into supramolecular layers oriented parallel to (20-1) by C—H⋯O interactions. These layers then stack in an ABAB pattern a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186108/ https://www.ncbi.nlm.nih.gov/pubmed/25309203 http://dx.doi.org/10.1107/S160053681401811X |
Sumario: | In the title co-crystal, C(25)H(32)N(4)O(2)·C(14)H(10)O(5), molecules are connected into supramolecular chains aligned along [102] by O—H⋯N hydrogen bonding. These aggregate into supramolecular layers oriented parallel to (20-1) by C—H⋯O interactions. These layers then stack in an ABAB pattern along the c crystal direction to give the full three-dimensional crystal structure. The central chain in the dipyridylamide has an anti–anti conformation. The dihedral angle between the aromatic ring planes is 29.96 (3)°. Disorder is noted in some of the residues in the structure and this is manifested in two coplanar dispositions of one statistically disordered carboxylic acid group. |
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