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Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1)
In the title co-crystal, C(25)H(32)N(4)O(2)·C(14)H(10)O(5), molecules are connected into supramolecular chains aligned along [102] by O—H⋯N hydrogen bonding. These aggregate into supramolecular layers oriented parallel to (20-1) by C—H⋯O interactions. These layers then stack in an ABAB pattern a...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186108/ https://www.ncbi.nlm.nih.gov/pubmed/25309203 http://dx.doi.org/10.1107/S160053681401811X |
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author | Low, Emily M. LaDuca, Robert L. |
author_facet | Low, Emily M. LaDuca, Robert L. |
author_sort | Low, Emily M. |
collection | PubMed |
description | In the title co-crystal, C(25)H(32)N(4)O(2)·C(14)H(10)O(5), molecules are connected into supramolecular chains aligned along [102] by O—H⋯N hydrogen bonding. These aggregate into supramolecular layers oriented parallel to (20-1) by C—H⋯O interactions. These layers then stack in an ABAB pattern along the c crystal direction to give the full three-dimensional crystal structure. The central chain in the dipyridylamide has an anti–anti conformation. The dihedral angle between the aromatic ring planes is 29.96 (3)°. Disorder is noted in some of the residues in the structure and this is manifested in two coplanar dispositions of one statistically disordered carboxylic acid group. |
format | Online Article Text |
id | pubmed-4186108 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41861082014-10-12 Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1) Low, Emily M. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title co-crystal, C(25)H(32)N(4)O(2)·C(14)H(10)O(5), molecules are connected into supramolecular chains aligned along [102] by O—H⋯N hydrogen bonding. These aggregate into supramolecular layers oriented parallel to (20-1) by C—H⋯O interactions. These layers then stack in an ABAB pattern along the c crystal direction to give the full three-dimensional crystal structure. The central chain in the dipyridylamide has an anti–anti conformation. The dihedral angle between the aromatic ring planes is 29.96 (3)°. Disorder is noted in some of the residues in the structure and this is manifested in two coplanar dispositions of one statistically disordered carboxylic acid group. International Union of Crystallography 2014-08-16 /pmc/articles/PMC4186108/ /pubmed/25309203 http://dx.doi.org/10.1107/S160053681401811X Text en © Low and LaDuca 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Low, Emily M. LaDuca, Robert L. Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1) |
title | Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1) |
title_full | Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1) |
title_fullStr | Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1) |
title_full_unstemmed | Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1) |
title_short | Crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1) |
title_sort | crystal structure of [propane-1,3-diylbis(piperidine-4,1-diyl)]bis[(pyridin-4-yl)methanone]–4,4′-oxydibenzoic acid (1/1) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186108/ https://www.ncbi.nlm.nih.gov/pubmed/25309203 http://dx.doi.org/10.1107/S160053681401811X |
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