Crystal structure of N-[3-(2-chloro­benzo­yl)-5-ethyl­thio­phen-2-yl]-2-[(E)-(2-hy­droxy­benzyl­idene)amino]­acetamide

In the title compound, C(22)H(19)ClN(2)O(3)S, the dihedral angle between the mean planes of the thio­phene ring and the chloro­phenyl and hy­droxy­phenyl rings are 70.1 (1) and 40.2 (4)°, respectively. The benzene rings are twisted with respect to each other by 88.9 (3)°. The imine bond lies in an E...

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Autores principales: Kaur, Manpreet, Jasinski, Jerry P., Kavitha, Channappa N., Yathirajan, Hemmige S., Byrappa, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186110/
https://www.ncbi.nlm.nih.gov/pubmed/25309197
http://dx.doi.org/10.1107/S1600536814018224
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author Kaur, Manpreet
Jasinski, Jerry P.
Kavitha, Channappa N.
Yathirajan, Hemmige S.
Byrappa, K.
author_facet Kaur, Manpreet
Jasinski, Jerry P.
Kavitha, Channappa N.
Yathirajan, Hemmige S.
Byrappa, K.
author_sort Kaur, Manpreet
collection PubMed
description In the title compound, C(22)H(19)ClN(2)O(3)S, the dihedral angle between the mean planes of the thio­phene ring and the chloro­phenyl and hy­droxy­phenyl rings are 70.1 (1) and 40.2 (4)°, respectively. The benzene rings are twisted with respect to each other by 88.9 (3)°. The imine bond lies in an E conformation. Intra­molecular O—H⋯N and N—H⋯O hydrogen bonds each generate S(6) ring motifs. In the crystal, weak C—H⋯O inter­actions link the mol­ecules, forming chains along the c axis and zigzag chains along the b axis, generating sheets lying parallel to (100).
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spelling pubmed-41861102014-10-12 Crystal structure of N-[3-(2-chloro­benzo­yl)-5-ethyl­thio­phen-2-yl]-2-[(E)-(2-hy­droxy­benzyl­idene)amino]­acetamide Kaur, Manpreet Jasinski, Jerry P. Kavitha, Channappa N. Yathirajan, Hemmige S. Byrappa, K. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(22)H(19)ClN(2)O(3)S, the dihedral angle between the mean planes of the thio­phene ring and the chloro­phenyl and hy­droxy­phenyl rings are 70.1 (1) and 40.2 (4)°, respectively. The benzene rings are twisted with respect to each other by 88.9 (3)°. The imine bond lies in an E conformation. Intra­molecular O—H⋯N and N—H⋯O hydrogen bonds each generate S(6) ring motifs. In the crystal, weak C—H⋯O inter­actions link the mol­ecules, forming chains along the c axis and zigzag chains along the b axis, generating sheets lying parallel to (100). International Union of Crystallography 2014-08-16 /pmc/articles/PMC4186110/ /pubmed/25309197 http://dx.doi.org/10.1107/S1600536814018224 Text en © Kaur et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kaur, Manpreet
Jasinski, Jerry P.
Kavitha, Channappa N.
Yathirajan, Hemmige S.
Byrappa, K.
Crystal structure of N-[3-(2-chloro­benzo­yl)-5-ethyl­thio­phen-2-yl]-2-[(E)-(2-hy­droxy­benzyl­idene)amino]­acetamide
title Crystal structure of N-[3-(2-chloro­benzo­yl)-5-ethyl­thio­phen-2-yl]-2-[(E)-(2-hy­droxy­benzyl­idene)amino]­acetamide
title_full Crystal structure of N-[3-(2-chloro­benzo­yl)-5-ethyl­thio­phen-2-yl]-2-[(E)-(2-hy­droxy­benzyl­idene)amino]­acetamide
title_fullStr Crystal structure of N-[3-(2-chloro­benzo­yl)-5-ethyl­thio­phen-2-yl]-2-[(E)-(2-hy­droxy­benzyl­idene)amino]­acetamide
title_full_unstemmed Crystal structure of N-[3-(2-chloro­benzo­yl)-5-ethyl­thio­phen-2-yl]-2-[(E)-(2-hy­droxy­benzyl­idene)amino]­acetamide
title_short Crystal structure of N-[3-(2-chloro­benzo­yl)-5-ethyl­thio­phen-2-yl]-2-[(E)-(2-hy­droxy­benzyl­idene)amino]­acetamide
title_sort crystal structure of n-[3-(2-chloro­benzo­yl)-5-ethyl­thio­phen-2-yl]-2-[(e)-(2-hy­droxy­benzyl­idene)amino]­acetamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186110/
https://www.ncbi.nlm.nih.gov/pubmed/25309197
http://dx.doi.org/10.1107/S1600536814018224
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