Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one

In the title Schiff base compound, C(21)H(19)NO(3), the conformation about the C=C bond is Z. The N—H group and carbonyl O atom form an intra­molecular N—H⋯O hydrogen bond with an S(6) ring motif. The benz­yloxy ring and the 2-hy­droxy-5-methyl­phenyl ring are inclined to the central six-membered ri...

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Autores principales: Ghichi, Nadir, Benosmane, Ali, Benboudiaf, Ali, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186113/
https://www.ncbi.nlm.nih.gov/pubmed/25309278
http://dx.doi.org/10.1107/S1600536814016936
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author Ghichi, Nadir
Benosmane, Ali
Benboudiaf, Ali
Merazig, Hocine
author_facet Ghichi, Nadir
Benosmane, Ali
Benboudiaf, Ali
Merazig, Hocine
author_sort Ghichi, Nadir
collection PubMed
description In the title Schiff base compound, C(21)H(19)NO(3), the conformation about the C=C bond is Z. The N—H group and carbonyl O atom form an intra­molecular N—H⋯O hydrogen bond with an S(6) ring motif. The benz­yloxy ring and the 2-hy­droxy-5-methyl­phenyl ring are inclined to the central six-membered ring by 13.68 (9) and 9.13 (8)°, respectively, and to one another by 21.95 (9)°. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming helical chains along [010].
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spelling pubmed-41861132014-10-12 Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one Ghichi, Nadir Benosmane, Ali Benboudiaf, Ali Merazig, Hocine Acta Crystallogr Sect E Struct Rep Online Data Reports In the title Schiff base compound, C(21)H(19)NO(3), the conformation about the C=C bond is Z. The N—H group and carbonyl O atom form an intra­molecular N—H⋯O hydrogen bond with an S(6) ring motif. The benz­yloxy ring and the 2-hy­droxy-5-methyl­phenyl ring are inclined to the central six-membered ring by 13.68 (9) and 9.13 (8)°, respectively, and to one another by 21.95 (9)°. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming helical chains along [010]. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186113/ /pubmed/25309278 http://dx.doi.org/10.1107/S1600536814016936 Text en © Ghichi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ghichi, Nadir
Benosmane, Ali
Benboudiaf, Ali
Merazig, Hocine
Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_full Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_fullStr Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_full_unstemmed Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_short Crystal structure of (Z)-3-benz­yloxy-6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
title_sort crystal structure of (z)-3-benz­yloxy-6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]cyclo­hexa-2,4-dien-1-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186113/
https://www.ncbi.nlm.nih.gov/pubmed/25309278
http://dx.doi.org/10.1107/S1600536814016936
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