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Crystal structure of bis{N-[2-(dimethylamino)ethyl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate
In the title compound, [Ni(C(13)H(17)N(3))(2)]Cl(2)·3.5H(2)O, the geometry of the NiN(6) complex cation is slightly distorted octahedral, with a facial arrangement of the two tridentate N-[2-(dimethylamino)ethyl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of tw...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186116/ https://www.ncbi.nlm.nih.gov/pubmed/25309190 http://dx.doi.org/10.1107/S1600536814019035 |
Sumario: | In the title compound, [Ni(C(13)H(17)N(3))(2)]Cl(2)·3.5H(2)O, the geometry of the NiN(6) complex cation is slightly distorted octahedral, with a facial arrangement of the two tridentate N-[2-(dimethylamino)ethyl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-molecules located on centres of inversion, together with two chloride counter-anions and 3.5 water molecules of solvation, one of which is disordered across an inversion centre. In the crystal, O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen-bonding interactions form a three-dimensional network structure. |
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