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Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate

In the title compound, [Ni(C(13)H(17)N(3))(2)]Cl(2)·3.5H(2)O, the geom­etry of the NiN(6) complex cation is slightly distorted octa­hedral, with a facial arrangement of the two tridentate N-[2-(di­­methyl­amino)­eth­yl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of tw...

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Detalles Bibliográficos
Autores principales: Kariuki, Benson M., Al-Sudani, Abdul-Razak H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186116/
https://www.ncbi.nlm.nih.gov/pubmed/25309190
http://dx.doi.org/10.1107/S1600536814019035
Descripción
Sumario:In the title compound, [Ni(C(13)H(17)N(3))(2)]Cl(2)·3.5H(2)O, the geom­etry of the NiN(6) complex cation is slightly distorted octa­hedral, with a facial arrangement of the two tridentate N-[2-(di­­methyl­amino)­eth­yl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-mol­ecules located on centres of inversion, together with two chloride counter-anions and 3.5 water mol­ecules of solvation, one of which is disordered across an inversion centre. In the crystal, O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen-bonding inter­actions form a three-dimensional network structure.