Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate

In the title compound, [Ni(C(13)H(17)N(3))(2)]Cl(2)·3.5H(2)O, the geom­etry of the NiN(6) complex cation is slightly distorted octa­hedral, with a facial arrangement of the two tridentate N-[2-(di­­methyl­amino)­eth­yl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of tw...

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Autores principales: Kariuki, Benson M., Al-Sudani, Abdul-Razak H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186116/
https://www.ncbi.nlm.nih.gov/pubmed/25309190
http://dx.doi.org/10.1107/S1600536814019035
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author Kariuki, Benson M.
Al-Sudani, Abdul-Razak H.
author_facet Kariuki, Benson M.
Al-Sudani, Abdul-Razak H.
author_sort Kariuki, Benson M.
collection PubMed
description In the title compound, [Ni(C(13)H(17)N(3))(2)]Cl(2)·3.5H(2)O, the geom­etry of the NiN(6) complex cation is slightly distorted octa­hedral, with a facial arrangement of the two tridentate N-[2-(di­­methyl­amino)­eth­yl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-mol­ecules located on centres of inversion, together with two chloride counter-anions and 3.5 water mol­ecules of solvation, one of which is disordered across an inversion centre. In the crystal, O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen-bonding inter­actions form a three-dimensional network structure.
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spelling pubmed-41861162014-10-12 Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate Kariuki, Benson M. Al-Sudani, Abdul-Razak H. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, [Ni(C(13)H(17)N(3))(2)]Cl(2)·3.5H(2)O, the geom­etry of the NiN(6) complex cation is slightly distorted octa­hedral, with a facial arrangement of the two tridentate N-[2-(di­­methyl­amino)­eth­yl]quinolin-8-amine ligands around the metal ion. The asymmetric unit consists of two independent complex half-mol­ecules located on centres of inversion, together with two chloride counter-anions and 3.5 water mol­ecules of solvation, one of which is disordered across an inversion centre. In the crystal, O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen-bonding inter­actions form a three-dimensional network structure. International Union of Crystallography 2014-08-30 /pmc/articles/PMC4186116/ /pubmed/25309190 http://dx.doi.org/10.1107/S1600536814019035 Text en © Kariuki and Al-Sudani 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kariuki, Benson M.
Al-Sudani, Abdul-Razak H.
Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate
title Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate
title_full Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate
title_fullStr Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate
title_full_unstemmed Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate
title_short Crystal structure of bis­{N-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) N,N′,N′′}nickel(II) dichloride 3.5-hydrate
title_sort crystal structure of bis­{n-[2-(di­methyl­amino)­eth­yl]quinolin-8-amine-κ(3) n,n′,n′′}nickel(ii) dichloride 3.5-hydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186116/
https://www.ncbi.nlm.nih.gov/pubmed/25309190
http://dx.doi.org/10.1107/S1600536814019035
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