Crystal structure of 5-iodo-2-methyl-3-[(4-methyl­phenyl)­sulfon­yl]-1-benzo­furan

In the title compound, C(16)H(13)IO(3)S, the dihedral angle between the planes of the benzo­furan ring system [r.m.s. deviation = 0.015 (2) Å] and the 4-methyl­phenyl ring is 70.35 (5)°. In the crystal, mol­ecules are linked by pairs of π–π inter­actions between the furan and benzene rings, with cen...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186123/
https://www.ncbi.nlm.nih.gov/pubmed/25309207
http://dx.doi.org/10.1107/S1600536814018510
Descripción
Sumario:In the title compound, C(16)H(13)IO(3)S, the dihedral angle between the planes of the benzo­furan ring system [r.m.s. deviation = 0.015 (2) Å] and the 4-methyl­phenyl ring is 70.35 (5)°. In the crystal, mol­ecules are linked by pairs of π–π inter­actions between the furan and benzene rings, with centroid–centroid distances of 3.667 (3) and 3.701 (3) Å. The mol­ecules stack along the a-axis direction. In addition, pairs of C—H⋯O hydrogen bonds between inversion-related dimers [which generate R (2) (2)(10) loops] and a short I⋯I [3.7534 (3) Å] contact are observed.

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