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Crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione)

In the structure of the title compound, C(46)H(37)N(3)O(4)S, the planes of the two isoindoline units make a dihedral angle of 77.86 (3)°. The dihedral angles between the benzyl plane and the isoindoline units are 79.56 (4) and 3.74 (9)°. The geometry at the S atom shows a short [1.7748 (17) Å] S—C(b...

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Detalles Bibliográficos
Autores principales: Flörke, Ulrich, Neuba, Adam, Ortmeyer, Jochen, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186125/
https://www.ncbi.nlm.nih.gov/pubmed/25309240
http://dx.doi.org/10.1107/S1600536814015554
Descripción
Sumario:In the structure of the title compound, C(46)H(37)N(3)O(4)S, the planes of the two isoindoline units make a dihedral angle of 77.86 (3)°. The dihedral angles between the benzyl plane and the isoindoline units are 79.56 (4) and 3.74 (9)°. The geometry at the S atom shows a short [1.7748 (17) Å] S—C(benz­yl) and a long [1.8820 (15) Å] S—C(trit­yl) bond and the C—S—C angle is 108.40 (7)°. N—C bond lengths around the azane N atom are in the range 1.454 (2)–1.463 (2) Å. he crystal packing exhibts two rather ‘non-classical’ C—H⋯O hydrogen bonds that result in stacking of the molecules along the a as well as the b axis and give rise to columnar sub-structures.