Crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione)

In the structure of the title compound, C(46)H(37)N(3)O(4)S, the planes of the two isoindoline units make a dihedral angle of 77.86 (3)°. The dihedral angles between the benzyl plane and the isoindoline units are 79.56 (4) and 3.74 (9)°. The geometry at the S atom shows a short [1.7748 (17) Å] S—C(b...

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Autores principales: Flörke, Ulrich, Neuba, Adam, Ortmeyer, Jochen, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186125/
https://www.ncbi.nlm.nih.gov/pubmed/25309240
http://dx.doi.org/10.1107/S1600536814015554
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author Flörke, Ulrich
Neuba, Adam
Ortmeyer, Jochen
Henkel, Gerald
author_facet Flörke, Ulrich
Neuba, Adam
Ortmeyer, Jochen
Henkel, Gerald
author_sort Flörke, Ulrich
collection PubMed
description In the structure of the title compound, C(46)H(37)N(3)O(4)S, the planes of the two isoindoline units make a dihedral angle of 77.86 (3)°. The dihedral angles between the benzyl plane and the isoindoline units are 79.56 (4) and 3.74 (9)°. The geometry at the S atom shows a short [1.7748 (17) Å] S—C(benz­yl) and a long [1.8820 (15) Å] S—C(trit­yl) bond and the C—S—C angle is 108.40 (7)°. N—C bond lengths around the azane N atom are in the range 1.454 (2)–1.463 (2) Å. he crystal packing exhibts two rather ‘non-classical’ C—H⋯O hydrogen bonds that result in stacking of the molecules along the a as well as the b axis and give rise to columnar sub-structures.
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spelling pubmed-41861252014-10-12 Crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione) Flörke, Ulrich Neuba, Adam Ortmeyer, Jochen Henkel, Gerald Acta Crystallogr Sect E Struct Rep Online Data Reports In the structure of the title compound, C(46)H(37)N(3)O(4)S, the planes of the two isoindoline units make a dihedral angle of 77.86 (3)°. The dihedral angles between the benzyl plane and the isoindoline units are 79.56 (4) and 3.74 (9)°. The geometry at the S atom shows a short [1.7748 (17) Å] S—C(benz­yl) and a long [1.8820 (15) Å] S—C(trit­yl) bond and the C—S—C angle is 108.40 (7)°. N—C bond lengths around the azane N atom are in the range 1.454 (2)–1.463 (2) Å. he crystal packing exhibts two rather ‘non-classical’ C—H⋯O hydrogen bonds that result in stacking of the molecules along the a as well as the b axis and give rise to columnar sub-structures. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186125/ /pubmed/25309240 http://dx.doi.org/10.1107/S1600536814015554 Text en © Flörke et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Flörke, Ulrich
Neuba, Adam
Ortmeyer, Jochen
Henkel, Gerald
Crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione)
title Crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione)
title_full Crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione)
title_fullStr Crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione)
title_full_unstemmed Crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione)
title_short Crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione)
title_sort crystal structure of 2,2′-({[2-(trityl­sulfan­yl)benz­yl]azane­diyl}bis­(ethane-2,1-di­yl))bis­(isoindoline-1,3-dione)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186125/
https://www.ncbi.nlm.nih.gov/pubmed/25309240
http://dx.doi.org/10.1107/S1600536814015554
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AT henkelgerald crystalstructureof222tritylsulfanylbenzylazanediylbisethane21diylbisisoindoline13dione

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