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Crystal structure of poly[aqua[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole](μ-naphthalene-1,4-dicarboxylato)nickel(II)]
In the title compound, [Ni(C(12)H(6)O(4))(C(21)H(18)N(4))(H(2)O)](n), the Ni(II) cation is coordinated by three carboxylate O atoms of two naphthalene-1,4-dicarboxylate anions, one water molecule and two N atoms of two 1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole (DFDI) ligands, givin...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186126/ https://www.ncbi.nlm.nih.gov/pubmed/25309182 http://dx.doi.org/10.1107/S1600536814017681 |
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author | Zou, Hengye Qi, Yanjuan |
author_facet | Zou, Hengye Qi, Yanjuan |
author_sort | Zou, Hengye |
collection | PubMed |
description | In the title compound, [Ni(C(12)H(6)O(4))(C(21)H(18)N(4))(H(2)O)](n), the Ni(II) cation is coordinated by three carboxylate O atoms of two naphthalene-1,4-dicarboxylate anions, one water molecule and two N atoms of two 1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole (DFDI) ligands, giving rise to a slightly distorted octahedral geometry. The Ni(II) ions are linked by the DFDI ligands into chains, which are further connected by the carboxylate anions into double chains that elongate in the the b-axis direction. These double chains are linked by centrosymmetric pairs of O—H⋯O hydrogen bonds into layers parallel to (10-1). The asymmetric unit consists of one crystallographically independent Ni(II) cation, one carboxylate and one DFDI ligand, as well as of one water molecule, all of them located in general positions. |
format | Online Article Text |
id | pubmed-4186126 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41861262014-10-12 Crystal structure of poly[aqua[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole](μ-naphthalene-1,4-dicarboxylato)nickel(II)] Zou, Hengye Qi, Yanjuan Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, [Ni(C(12)H(6)O(4))(C(21)H(18)N(4))(H(2)O)](n), the Ni(II) cation is coordinated by three carboxylate O atoms of two naphthalene-1,4-dicarboxylate anions, one water molecule and two N atoms of two 1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole (DFDI) ligands, giving rise to a slightly distorted octahedral geometry. The Ni(II) ions are linked by the DFDI ligands into chains, which are further connected by the carboxylate anions into double chains that elongate in the the b-axis direction. These double chains are linked by centrosymmetric pairs of O—H⋯O hydrogen bonds into layers parallel to (10-1). The asymmetric unit consists of one crystallographically independent Ni(II) cation, one carboxylate and one DFDI ligand, as well as of one water molecule, all of them located in general positions. International Union of Crystallography 2014-08-06 /pmc/articles/PMC4186126/ /pubmed/25309182 http://dx.doi.org/10.1107/S1600536814017681 Text en © Zou and Qi 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Zou, Hengye Qi, Yanjuan Crystal structure of poly[aqua[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole](μ-naphthalene-1,4-dicarboxylato)nickel(II)] |
title | Crystal structure of poly[aqua[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole](μ-naphthalene-1,4-dicarboxylato)nickel(II)] |
title_full | Crystal structure of poly[aqua[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole](μ-naphthalene-1,4-dicarboxylato)nickel(II)] |
title_fullStr | Crystal structure of poly[aqua[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole](μ-naphthalene-1,4-dicarboxylato)nickel(II)] |
title_full_unstemmed | Crystal structure of poly[aqua[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole](μ-naphthalene-1,4-dicarboxylato)nickel(II)] |
title_short | Crystal structure of poly[aqua[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-diyl)di-1H-imidazole](μ-naphthalene-1,4-dicarboxylato)nickel(II)] |
title_sort | crystal structure of poly[aqua[μ-1,1′-(9,9-dimethyl-9h-fluoren-2,7-diyl)di-1h-imidazole](μ-naphthalene-1,4-dicarboxylato)nickel(ii)] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186126/ https://www.ncbi.nlm.nih.gov/pubmed/25309182 http://dx.doi.org/10.1107/S1600536814017681 |
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