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Crystal structure of poly[aqua­[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole](μ-naphthalene-1,4-di­carboxyl­ato)nickel(II)]

In the title compound, [Ni(C(12)H(6)O(4))(C(21)H(18)N(4))(H(2)O)](n), the Ni(II) cation is coordinated by three carboxyl­ate O atoms of two naphthalene-1,4-di­carboxyl­ate anions, one water mol­ecule and two N atoms of two 1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole (DFDI) ligands, givin...

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Autores principales: Zou, Hengye, Qi, Yanjuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186126/
https://www.ncbi.nlm.nih.gov/pubmed/25309182
http://dx.doi.org/10.1107/S1600536814017681
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author Zou, Hengye
Qi, Yanjuan
author_facet Zou, Hengye
Qi, Yanjuan
author_sort Zou, Hengye
collection PubMed
description In the title compound, [Ni(C(12)H(6)O(4))(C(21)H(18)N(4))(H(2)O)](n), the Ni(II) cation is coordinated by three carboxyl­ate O atoms of two naphthalene-1,4-di­carboxyl­ate anions, one water mol­ecule and two N atoms of two 1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole (DFDI) ligands, giving rise to a slightly distorted octa­hedral geometry. The Ni(II) ions are linked by the DFDI ligands into chains, which are further connected by the carboxyl­ate anions into double chains that elongate in the the b-axis direction. These double chains are linked by centrosymmetric pairs of O—H⋯O hydrogen bonds into layers parallel to (10-1). The asymmetric unit consists of one crystallographically independent Ni(II) cation, one carboxyl­ate and one DFDI ligand, as well as of one water mol­ecule, all of them located in general positions.
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spelling pubmed-41861262014-10-12 Crystal structure of poly[aqua­[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole](μ-naphthalene-1,4-di­carboxyl­ato)nickel(II)] Zou, Hengye Qi, Yanjuan Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, [Ni(C(12)H(6)O(4))(C(21)H(18)N(4))(H(2)O)](n), the Ni(II) cation is coordinated by three carboxyl­ate O atoms of two naphthalene-1,4-di­carboxyl­ate anions, one water mol­ecule and two N atoms of two 1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole (DFDI) ligands, giving rise to a slightly distorted octa­hedral geometry. The Ni(II) ions are linked by the DFDI ligands into chains, which are further connected by the carboxyl­ate anions into double chains that elongate in the the b-axis direction. These double chains are linked by centrosymmetric pairs of O—H⋯O hydrogen bonds into layers parallel to (10-1). The asymmetric unit consists of one crystallographically independent Ni(II) cation, one carboxyl­ate and one DFDI ligand, as well as of one water mol­ecule, all of them located in general positions. International Union of Crystallography 2014-08-06 /pmc/articles/PMC4186126/ /pubmed/25309182 http://dx.doi.org/10.1107/S1600536814017681 Text en © Zou and Qi 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Zou, Hengye
Qi, Yanjuan
Crystal structure of poly[aqua­[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole](μ-naphthalene-1,4-di­carboxyl­ato)nickel(II)]
title Crystal structure of poly[aqua­[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole](μ-naphthalene-1,4-di­carboxyl­ato)nickel(II)]
title_full Crystal structure of poly[aqua­[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole](μ-naphthalene-1,4-di­carboxyl­ato)nickel(II)]
title_fullStr Crystal structure of poly[aqua­[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole](μ-naphthalene-1,4-di­carboxyl­ato)nickel(II)]
title_full_unstemmed Crystal structure of poly[aqua­[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole](μ-naphthalene-1,4-di­carboxyl­ato)nickel(II)]
title_short Crystal structure of poly[aqua­[μ-1,1′-(9,9-dimethyl-9H-fluoren-2,7-di­yl)di-1H-imidazole](μ-naphthalene-1,4-di­carboxyl­ato)nickel(II)]
title_sort crystal structure of poly[aqua­[μ-1,1′-(9,9-dimethyl-9h-fluoren-2,7-di­yl)di-1h-imidazole](μ-naphthalene-1,4-di­carboxyl­ato)nickel(ii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186126/
https://www.ncbi.nlm.nih.gov/pubmed/25309182
http://dx.doi.org/10.1107/S1600536814017681
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