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Crystal structure of 2,7-dieth­oxy-1,8-bis­(4-nitro­benzo­yl)naphthalene

The title compound, C(28)H(22)N(2)O(8), possesses crystallographically imposed twofold symmetry, with the two central carbon atoms of the naphthalene unit lying on the rotation axis. The two benzoyl groups in the mol­ecule are twisted away from the attached naphthalene unit with a C—C—C=O torsion an...

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Autores principales: Mohri, Saki, Ohisa, Shinji, Noguchi, Keiichi, Yonezawa, Noriyuki, Okamoto, Akiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186128/
https://www.ncbi.nlm.nih.gov/pubmed/25309162
http://dx.doi.org/10.1107/S1600536814018674
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author Mohri, Saki
Ohisa, Shinji
Noguchi, Keiichi
Yonezawa, Noriyuki
Okamoto, Akiko
author_facet Mohri, Saki
Ohisa, Shinji
Noguchi, Keiichi
Yonezawa, Noriyuki
Okamoto, Akiko
author_sort Mohri, Saki
collection PubMed
description The title compound, C(28)H(22)N(2)O(8), possesses crystallographically imposed twofold symmetry, with the two central carbon atoms of the naphthalene unit lying on the rotation axis. The two benzoyl groups in the mol­ecule are twisted away from the attached naphthalene unit with a C—C—C=O torsion angle of 49.05 (15)° between the naphthalene unit and the carbonyl group. The dihedral angle between the naphthalene ring system and the benzene ring is 77.17 (5)°. In the crystal, pairs of C—H⋯O=C hydrogen bonds link the mol­ecules into a double-column structure along the c axis. The mol­ecules are further linked by C—H⋯O=N hydrogen bonds, forming a three-dimensional network. C—H⋯π inter­actions between the methyl­ene group and the naphthalene unit and π–π inter­actions between the naphthalene ring systems [centroid–centroid distances of 3.7858 (7)–3.7860 (7) Å] are also observed.
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spelling pubmed-41861282014-10-12 Crystal structure of 2,7-dieth­oxy-1,8-bis­(4-nitro­benzo­yl)naphthalene Mohri, Saki Ohisa, Shinji Noguchi, Keiichi Yonezawa, Noriyuki Okamoto, Akiko Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, C(28)H(22)N(2)O(8), possesses crystallographically imposed twofold symmetry, with the two central carbon atoms of the naphthalene unit lying on the rotation axis. The two benzoyl groups in the mol­ecule are twisted away from the attached naphthalene unit with a C—C—C=O torsion angle of 49.05 (15)° between the naphthalene unit and the carbonyl group. The dihedral angle between the naphthalene ring system and the benzene ring is 77.17 (5)°. In the crystal, pairs of C—H⋯O=C hydrogen bonds link the mol­ecules into a double-column structure along the c axis. The mol­ecules are further linked by C—H⋯O=N hydrogen bonds, forming a three-dimensional network. C—H⋯π inter­actions between the methyl­ene group and the naphthalene unit and π–π inter­actions between the naphthalene ring systems [centroid–centroid distances of 3.7858 (7)–3.7860 (7) Å] are also observed. International Union of Crystallography 2014-08-23 /pmc/articles/PMC4186128/ /pubmed/25309162 http://dx.doi.org/10.1107/S1600536814018674 Text en © Mohri et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Mohri, Saki
Ohisa, Shinji
Noguchi, Keiichi
Yonezawa, Noriyuki
Okamoto, Akiko
Crystal structure of 2,7-dieth­oxy-1,8-bis­(4-nitro­benzo­yl)naphthalene
title Crystal structure of 2,7-dieth­oxy-1,8-bis­(4-nitro­benzo­yl)naphthalene
title_full Crystal structure of 2,7-dieth­oxy-1,8-bis­(4-nitro­benzo­yl)naphthalene
title_fullStr Crystal structure of 2,7-dieth­oxy-1,8-bis­(4-nitro­benzo­yl)naphthalene
title_full_unstemmed Crystal structure of 2,7-dieth­oxy-1,8-bis­(4-nitro­benzo­yl)naphthalene
title_short Crystal structure of 2,7-dieth­oxy-1,8-bis­(4-nitro­benzo­yl)naphthalene
title_sort crystal structure of 2,7-dieth­oxy-1,8-bis­(4-nitro­benzo­yl)naphthalene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186128/
https://www.ncbi.nlm.nih.gov/pubmed/25309162
http://dx.doi.org/10.1107/S1600536814018674
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