Crystal structure of bis­(acetato-κO)bis­(pyridine-2-carboxamide oxime-κ(2) N,N′)cadmium ethanol disolvate

In the title compound, [Cd(CH(3)COO)(2)(C(6)H(7)N(3)O)(2)]·2C(2)H(5)OH, the Cd(II) atom, which lies on a twofold rotation axis, is coordinated by two monodentate acetate groups and two N,N′-chelating pyridine-2-carboxamide oxime ligands, leading to a distorted octahedral coordination sphere. The mon...

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Detalles Bibliográficos
Autor principal: Liu, Jiyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186130/
https://www.ncbi.nlm.nih.gov/pubmed/25309163
http://dx.doi.org/10.1107/S1600536814017978
Descripción
Sumario:In the title compound, [Cd(CH(3)COO)(2)(C(6)H(7)N(3)O)(2)]·2C(2)H(5)OH, the Cd(II) atom, which lies on a twofold rotation axis, is coordinated by two monodentate acetate groups and two N,N′-chelating pyridine-2-carboxamide oxime ligands, leading to a distorted octahedral coordination sphere. The mononuclear complex mol­ecules are assembled into chains along the c-axis direction via N—H⋯O hydrogen-bonding inter­actions. These chains are further assembled by O—H⋯O hydrogen bonds involving the ethanol solvent mol­ecules into a three-dimensional supramolecular structure.

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