Crystal structure of bis­(acetato-κO)bis­(pyridine-2-carboxamide oxime-κ(2) N,N′)cadmium ethanol disolvate

In the title compound, [Cd(CH(3)COO)(2)(C(6)H(7)N(3)O)(2)]·2C(2)H(5)OH, the Cd(II) atom, which lies on a twofold rotation axis, is coordinated by two monodentate acetate groups and two N,N′-chelating pyridine-2-carboxamide oxime ligands, leading to a distorted octahedral coordination sphere. The mon...

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Detalles Bibliográficos
Autor principal: Liu, Jiyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186130/
https://www.ncbi.nlm.nih.gov/pubmed/25309163
http://dx.doi.org/10.1107/S1600536814017978
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author Liu, Jiyong
author_facet Liu, Jiyong
author_sort Liu, Jiyong
collection PubMed
description In the title compound, [Cd(CH(3)COO)(2)(C(6)H(7)N(3)O)(2)]·2C(2)H(5)OH, the Cd(II) atom, which lies on a twofold rotation axis, is coordinated by two monodentate acetate groups and two N,N′-chelating pyridine-2-carboxamide oxime ligands, leading to a distorted octahedral coordination sphere. The mononuclear complex mol­ecules are assembled into chains along the c-axis direction via N—H⋯O hydrogen-bonding inter­actions. These chains are further assembled by O—H⋯O hydrogen bonds involving the ethanol solvent mol­ecules into a three-dimensional supramolecular structure.
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spelling pubmed-41861302014-10-12 Crystal structure of bis­(acetato-κO)bis­(pyridine-2-carboxamide oxime-κ(2) N,N′)cadmium ethanol disolvate Liu, Jiyong Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, [Cd(CH(3)COO)(2)(C(6)H(7)N(3)O)(2)]·2C(2)H(5)OH, the Cd(II) atom, which lies on a twofold rotation axis, is coordinated by two monodentate acetate groups and two N,N′-chelating pyridine-2-carboxamide oxime ligands, leading to a distorted octahedral coordination sphere. The mononuclear complex mol­ecules are assembled into chains along the c-axis direction via N—H⋯O hydrogen-bonding inter­actions. These chains are further assembled by O—H⋯O hydrogen bonds involving the ethanol solvent mol­ecules into a three-dimensional supramolecular structure. International Union of Crystallography 2014-08-23 /pmc/articles/PMC4186130/ /pubmed/25309163 http://dx.doi.org/10.1107/S1600536814017978 Text en © Jiyong Liu 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Liu, Jiyong
Crystal structure of bis­(acetato-κO)bis­(pyridine-2-carboxamide oxime-κ(2) N,N′)cadmium ethanol disolvate
title Crystal structure of bis­(acetato-κO)bis­(pyridine-2-carboxamide oxime-κ(2) N,N′)cadmium ethanol disolvate
title_full Crystal structure of bis­(acetato-κO)bis­(pyridine-2-carboxamide oxime-κ(2) N,N′)cadmium ethanol disolvate
title_fullStr Crystal structure of bis­(acetato-κO)bis­(pyridine-2-carboxamide oxime-κ(2) N,N′)cadmium ethanol disolvate
title_full_unstemmed Crystal structure of bis­(acetato-κO)bis­(pyridine-2-carboxamide oxime-κ(2) N,N′)cadmium ethanol disolvate
title_short Crystal structure of bis­(acetato-κO)bis­(pyridine-2-carboxamide oxime-κ(2) N,N′)cadmium ethanol disolvate
title_sort crystal structure of bis­(acetato-κo)bis­(pyridine-2-carboxamide oxime-κ(2) n,n′)cadmium ethanol disolvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186130/
https://www.ncbi.nlm.nih.gov/pubmed/25309163
http://dx.doi.org/10.1107/S1600536814017978
work_keys_str_mv AT liujiyong crystalstructureofbisacetatokobispyridine2carboxamideoximek2nncadmiumethanoldisolvate

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