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Crystal structure of (Z)-2,3-dichloro-1,4-bis(4-methoxyphenyl)but-2-ene-1,4-dione
The title compound, C(18)H(14)Cl(2)O(4), adopts a Z conformation around the cental C=C bond. The two aromatic rings of the molecule are nearly perpendicular to each other, with a dihedral angle between of 86.22 (14)°. The methoxy substituents lie close to the plane of the attached benzene rings. T...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186131/ https://www.ncbi.nlm.nih.gov/pubmed/25309219 http://dx.doi.org/10.1107/S1600536814018790 |
Sumario: | The title compound, C(18)H(14)Cl(2)O(4), adopts a Z conformation around the cental C=C bond. The two aromatic rings of the molecule are nearly perpendicular to each other, with a dihedral angle between of 86.22 (14)°. The methoxy substituents lie close to the plane of the attached benzene rings. The C(ar)—C(ar)—O—C(Me) torsion angles are −2.4 (7) and 7.5 (6)°. Weak C—H⋯O interactions link the molecules forming a three-dimensional network. The crystal packing also displays short [3.160 (3) Å] Cl⋯O halogen-bonding contacts between molecules related by the screw axis. The structure exhibits disorder of one carbonyl O atom with a refined occupancy ratio of 0.21 (6):0.79 (6). |
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