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Crystal structure of (Z)-2,3-di­chloro-1,4-bis­(4-meth­oxy­phen­yl)but-2-ene-1,4-dione

The title compound, C(18)H(14)Cl(2)O(4), adopts a Z conformation around the cental C=C bond. The two aromatic rings of the mol­ecule are nearly perpendicular to each other, with a dihedral angle between of 86.22 (14)°. The meth­oxy substituents lie close to the plane of the attached benzene rings. T...

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Detalles Bibliográficos
Autores principales: Tittal, Ram K., Kumar, Satish, Ram, R. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186131/
https://www.ncbi.nlm.nih.gov/pubmed/25309219
http://dx.doi.org/10.1107/S1600536814018790
Descripción
Sumario:The title compound, C(18)H(14)Cl(2)O(4), adopts a Z conformation around the cental C=C bond. The two aromatic rings of the mol­ecule are nearly perpendicular to each other, with a dihedral angle between of 86.22 (14)°. The meth­oxy substituents lie close to the plane of the attached benzene rings. The C(ar)—C(ar)—O—C(Me) torsion angles are −2.4 (7) and 7.5 (6)°. Weak C—H⋯O inter­actions link the mol­ecules forming a three-dimensional network. The crystal packing also displays short [3.160 (3) Å] Cl⋯O halogen-bonding contacts between mol­ecules related by the screw axis. The structure exhibits disorder of one carbonyl O atom with a refined occupancy ratio of 0.21 (6):0.79 (6).