Crystal structure of 2,9-diphenyl-17λ(6)-thia­tetra­cyclo­[8.7.0.0(3,8).0(11,16)]hepta­deca-1(10),2,4,6,8,11(16),12,14-octa­ene-17,17-dione

The title compound, C(28)H(18)O(2)S, is composed of a naphthalene ring system fused with a benzo­thio­phene ring and attached to two phenyl rings. The phenyl rings make dihedral angles of 70.92 (8) and 79.23 (8)° with the essentially planar naphthalene ring system (r.m.s. deviation = 0.031 Å). There...

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Detalles Bibliográficos
Autores principales: Gopinath, S., Narayanan, P., Sethusankar, K., Nandakumar, Meganathan, Mohanakrishnan, Arasambattu K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186134/
https://www.ncbi.nlm.nih.gov/pubmed/25309198
http://dx.doi.org/10.1107/S1600536814017838
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author Gopinath, S.
Narayanan, P.
Sethusankar, K.
Nandakumar, Meganathan
Mohanakrishnan, Arasambattu K.
author_facet Gopinath, S.
Narayanan, P.
Sethusankar, K.
Nandakumar, Meganathan
Mohanakrishnan, Arasambattu K.
author_sort Gopinath, S.
collection PubMed
description The title compound, C(28)H(18)O(2)S, is composed of a naphthalene ring system fused with a benzo­thio­phene ring and attached to two phenyl rings. The phenyl rings make dihedral angles of 70.92 (8) and 79.23 (8)° with the essentially planar naphthalene ring system (r.m.s. deviation = 0.031 Å). There is an intra­molecular C—H⋯π inter­action present. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds which generate C(7) zigzag chains running parallel to [10-1]. The chains are linked via further C—H⋯π inter­actions, forming a three-dimensional structure.
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spelling pubmed-41861342014-10-12 Crystal structure of 2,9-diphenyl-17λ(6)-thia­tetra­cyclo­[8.7.0.0(3,8).0(11,16)]hepta­deca-1(10),2,4,6,8,11(16),12,14-octa­ene-17,17-dione Gopinath, S. Narayanan, P. Sethusankar, K. Nandakumar, Meganathan Mohanakrishnan, Arasambattu K. Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, C(28)H(18)O(2)S, is composed of a naphthalene ring system fused with a benzo­thio­phene ring and attached to two phenyl rings. The phenyl rings make dihedral angles of 70.92 (8) and 79.23 (8)° with the essentially planar naphthalene ring system (r.m.s. deviation = 0.031 Å). There is an intra­molecular C—H⋯π inter­action present. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds which generate C(7) zigzag chains running parallel to [10-1]. The chains are linked via further C—H⋯π inter­actions, forming a three-dimensional structure. International Union of Crystallography 2014-08-16 /pmc/articles/PMC4186134/ /pubmed/25309198 http://dx.doi.org/10.1107/S1600536814017838 Text en © Gopinath et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Gopinath, S.
Narayanan, P.
Sethusankar, K.
Nandakumar, Meganathan
Mohanakrishnan, Arasambattu K.
Crystal structure of 2,9-diphenyl-17λ(6)-thia­tetra­cyclo­[8.7.0.0(3,8).0(11,16)]hepta­deca-1(10),2,4,6,8,11(16),12,14-octa­ene-17,17-dione
title Crystal structure of 2,9-diphenyl-17λ(6)-thia­tetra­cyclo­[8.7.0.0(3,8).0(11,16)]hepta­deca-1(10),2,4,6,8,11(16),12,14-octa­ene-17,17-dione
title_full Crystal structure of 2,9-diphenyl-17λ(6)-thia­tetra­cyclo­[8.7.0.0(3,8).0(11,16)]hepta­deca-1(10),2,4,6,8,11(16),12,14-octa­ene-17,17-dione
title_fullStr Crystal structure of 2,9-diphenyl-17λ(6)-thia­tetra­cyclo­[8.7.0.0(3,8).0(11,16)]hepta­deca-1(10),2,4,6,8,11(16),12,14-octa­ene-17,17-dione
title_full_unstemmed Crystal structure of 2,9-diphenyl-17λ(6)-thia­tetra­cyclo­[8.7.0.0(3,8).0(11,16)]hepta­deca-1(10),2,4,6,8,11(16),12,14-octa­ene-17,17-dione
title_short Crystal structure of 2,9-diphenyl-17λ(6)-thia­tetra­cyclo­[8.7.0.0(3,8).0(11,16)]hepta­deca-1(10),2,4,6,8,11(16),12,14-octa­ene-17,17-dione
title_sort crystal structure of 2,9-diphenyl-17λ(6)-thia­tetra­cyclo­[8.7.0.0(3,8).0(11,16)]hepta­deca-1(10),2,4,6,8,11(16),12,14-octa­ene-17,17-dione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186134/
https://www.ncbi.nlm.nih.gov/pubmed/25309198
http://dx.doi.org/10.1107/S1600536814017838
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