Crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ(3) O,N,O′)bis(propan-2-olato-κO)titanium(IV)

In the mononuclear Ti(IV) title complex, [Ti(C(29)H(33)NO(2))(C(3)H(6)O)(2)], the TiNO(4) coordination polyhedron comprises an N-atom and two O-atom donors from the dianionic Schiff base ligand and two O-atom donors from monodentate isopropoxide anions. The stereochemistry is distorted trigonal–bipy...

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Detalles Bibliográficos
Autores principales: Chen, Liang, Wang, Huiran, Deng, Xuebin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186137/
https://www.ncbi.nlm.nih.gov/pubmed/25309186
http://dx.doi.org/10.1107/S1600536814018455
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author Chen, Liang
Wang, Huiran
Deng, Xuebin
author_facet Chen, Liang
Wang, Huiran
Deng, Xuebin
author_sort Chen, Liang
collection PubMed
description In the mononuclear Ti(IV) title complex, [Ti(C(29)H(33)NO(2))(C(3)H(6)O)(2)], the TiNO(4) coordination polyhedron comprises an N-atom and two O-atom donors from the dianionic Schiff base ligand and two O-atom donors from monodentate isopropoxide anions. The stereochemistry is distorted trigonal–bipyramidal with the N-donor in an elongated axial site [Ti—N = 2.2540 (17) Å], the O-donors having normal Ti—O bond lengths [1.7937 (14) Å (axial)–1.8690 (14) Å]. In the crystal, C—H⋯π inter­actions link mol­ecules into centrosymmetric dimers.
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spelling pubmed-41861372014-10-12 Crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ(3) O,N,O′)bis(propan-2-olato-κO)titanium(IV) Chen, Liang Wang, Huiran Deng, Xuebin Acta Crystallogr Sect E Struct Rep Online Data Reports In the mononuclear Ti(IV) title complex, [Ti(C(29)H(33)NO(2))(C(3)H(6)O)(2)], the TiNO(4) coordination polyhedron comprises an N-atom and two O-atom donors from the dianionic Schiff base ligand and two O-atom donors from monodentate isopropoxide anions. The stereochemistry is distorted trigonal–bipyramidal with the N-donor in an elongated axial site [Ti—N = 2.2540 (17) Å], the O-donors having normal Ti—O bond lengths [1.7937 (14) Å (axial)–1.8690 (14) Å]. In the crystal, C—H⋯π inter­actions link mol­ecules into centrosymmetric dimers. International Union of Crystallography 2014-08-16 /pmc/articles/PMC4186137/ /pubmed/25309186 http://dx.doi.org/10.1107/S1600536814018455 Text en © Chen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Chen, Liang
Wang, Huiran
Deng, Xuebin
Crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ(3) O,N,O′)bis(propan-2-olato-κO)titanium(IV)
title Crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ(3) O,N,O′)bis(propan-2-olato-κO)titanium(IV)
title_full Crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ(3) O,N,O′)bis(propan-2-olato-κO)titanium(IV)
title_fullStr Crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ(3) O,N,O′)bis(propan-2-olato-κO)titanium(IV)
title_full_unstemmed Crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ(3) O,N,O′)bis(propan-2-olato-κO)titanium(IV)
title_short Crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ(3) O,N,O′)bis(propan-2-olato-κO)titanium(IV)
title_sort crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ(3) o,n,o′)bis(propan-2-olato-κo)titanium(iv)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186137/
https://www.ncbi.nlm.nih.gov/pubmed/25309186
http://dx.doi.org/10.1107/S1600536814018455
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