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Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)meth­oxy]benzyl­idene}[2-(morpholin-4-yl)eth­yl]amine

In the title compound, C(19)H(25)N(5)O(2), the morpholine ring has a chair conformation. The plane of the central benzene ring makes dihedral angles of 88.75 (12) and 60.02 (7)°, respectively, with the mean plane formed by the four planar C atoms of the morpholine ring and with the plane of the tria...

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Autores principales: Çelikesir, Sevim Türktekin, Akkurt, Mehmet, Jarrahpour, Aliasghar, Chermahini, Mehdi Mohammadi, Shiri, Pezhman, Büyükgüngör, Orhan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186139/
https://www.ncbi.nlm.nih.gov/pubmed/25309262
http://dx.doi.org/10.1107/S1600536814016754
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author Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Jarrahpour, Aliasghar
Chermahini, Mehdi Mohammadi
Shiri, Pezhman
Büyükgüngör, Orhan
author_facet Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Jarrahpour, Aliasghar
Chermahini, Mehdi Mohammadi
Shiri, Pezhman
Büyükgüngör, Orhan
author_sort Çelikesir, Sevim Türktekin
collection PubMed
description In the title compound, C(19)H(25)N(5)O(2), the morpholine ring has a chair conformation. The plane of the central benzene ring makes dihedral angles of 88.75 (12) and 60.02 (7)°, respectively, with the mean plane formed by the four planar C atoms of the morpholine ring and with the plane of the triazole ring. In the crystal, mol­ecules are linked via C—H⋯π inter­actions, forming slabs lying parallel to (10-1). The C atoms of the bridging ethyl­ene group, between the morpholine and benzene rings, and the terminal ethene group of the prop-1-ene substituent attached to the triazole ring, are disordered over two sets of sites, with an occupancy ratio of 0.634 (13):0.366 (13).
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spelling pubmed-41861392014-10-12 Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)meth­oxy]benzyl­idene}[2-(morpholin-4-yl)eth­yl]amine Çelikesir, Sevim Türktekin Akkurt, Mehmet Jarrahpour, Aliasghar Chermahini, Mehdi Mohammadi Shiri, Pezhman Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(19)H(25)N(5)O(2), the morpholine ring has a chair conformation. The plane of the central benzene ring makes dihedral angles of 88.75 (12) and 60.02 (7)°, respectively, with the mean plane formed by the four planar C atoms of the morpholine ring and with the plane of the triazole ring. In the crystal, mol­ecules are linked via C—H⋯π inter­actions, forming slabs lying parallel to (10-1). The C atoms of the bridging ethyl­ene group, between the morpholine and benzene rings, and the terminal ethene group of the prop-1-ene substituent attached to the triazole ring, are disordered over two sets of sites, with an occupancy ratio of 0.634 (13):0.366 (13). International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186139/ /pubmed/25309262 http://dx.doi.org/10.1107/S1600536814016754 Text en © Çelikesir et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Çelikesir, Sevim Türktekin
Akkurt, Mehmet
Jarrahpour, Aliasghar
Chermahini, Mehdi Mohammadi
Shiri, Pezhman
Büyükgüngör, Orhan
Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)meth­oxy]benzyl­idene}[2-(morpholin-4-yl)eth­yl]amine
title Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)meth­oxy]benzyl­idene}[2-(morpholin-4-yl)eth­yl]amine
title_full Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)meth­oxy]benzyl­idene}[2-(morpholin-4-yl)eth­yl]amine
title_fullStr Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)meth­oxy]benzyl­idene}[2-(morpholin-4-yl)eth­yl]amine
title_full_unstemmed Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)meth­oxy]benzyl­idene}[2-(morpholin-4-yl)eth­yl]amine
title_short Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)meth­oxy]benzyl­idene}[2-(morpholin-4-yl)eth­yl]amine
title_sort crystal structure of {(e)-4-[(1-allyl-1h-1,2,3-triazol-4-yl)meth­oxy]benzyl­idene}[2-(morpholin-4-yl)eth­yl]amine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186139/
https://www.ncbi.nlm.nih.gov/pubmed/25309262
http://dx.doi.org/10.1107/S1600536814016754
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