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Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)methoxy]benzylidene}[2-(morpholin-4-yl)ethyl]amine
In the title compound, C(19)H(25)N(5)O(2), the morpholine ring has a chair conformation. The plane of the central benzene ring makes dihedral angles of 88.75 (12) and 60.02 (7)°, respectively, with the mean plane formed by the four planar C atoms of the morpholine ring and with the plane of the tria...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186139/ https://www.ncbi.nlm.nih.gov/pubmed/25309262 http://dx.doi.org/10.1107/S1600536814016754 |
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author | Çelikesir, Sevim Türktekin Akkurt, Mehmet Jarrahpour, Aliasghar Chermahini, Mehdi Mohammadi Shiri, Pezhman Büyükgüngör, Orhan |
author_facet | Çelikesir, Sevim Türktekin Akkurt, Mehmet Jarrahpour, Aliasghar Chermahini, Mehdi Mohammadi Shiri, Pezhman Büyükgüngör, Orhan |
author_sort | Çelikesir, Sevim Türktekin |
collection | PubMed |
description | In the title compound, C(19)H(25)N(5)O(2), the morpholine ring has a chair conformation. The plane of the central benzene ring makes dihedral angles of 88.75 (12) and 60.02 (7)°, respectively, with the mean plane formed by the four planar C atoms of the morpholine ring and with the plane of the triazole ring. In the crystal, molecules are linked via C—H⋯π interactions, forming slabs lying parallel to (10-1). The C atoms of the bridging ethylene group, between the morpholine and benzene rings, and the terminal ethene group of the prop-1-ene substituent attached to the triazole ring, are disordered over two sets of sites, with an occupancy ratio of 0.634 (13):0.366 (13). |
format | Online Article Text |
id | pubmed-4186139 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41861392014-10-12 Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)methoxy]benzylidene}[2-(morpholin-4-yl)ethyl]amine Çelikesir, Sevim Türktekin Akkurt, Mehmet Jarrahpour, Aliasghar Chermahini, Mehdi Mohammadi Shiri, Pezhman Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(19)H(25)N(5)O(2), the morpholine ring has a chair conformation. The plane of the central benzene ring makes dihedral angles of 88.75 (12) and 60.02 (7)°, respectively, with the mean plane formed by the four planar C atoms of the morpholine ring and with the plane of the triazole ring. In the crystal, molecules are linked via C—H⋯π interactions, forming slabs lying parallel to (10-1). The C atoms of the bridging ethylene group, between the morpholine and benzene rings, and the terminal ethene group of the prop-1-ene substituent attached to the triazole ring, are disordered over two sets of sites, with an occupancy ratio of 0.634 (13):0.366 (13). International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186139/ /pubmed/25309262 http://dx.doi.org/10.1107/S1600536814016754 Text en © Çelikesir et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Çelikesir, Sevim Türktekin Akkurt, Mehmet Jarrahpour, Aliasghar Chermahini, Mehdi Mohammadi Shiri, Pezhman Büyükgüngör, Orhan Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)methoxy]benzylidene}[2-(morpholin-4-yl)ethyl]amine |
title | Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)methoxy]benzylidene}[2-(morpholin-4-yl)ethyl]amine |
title_full | Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)methoxy]benzylidene}[2-(morpholin-4-yl)ethyl]amine |
title_fullStr | Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)methoxy]benzylidene}[2-(morpholin-4-yl)ethyl]amine |
title_full_unstemmed | Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)methoxy]benzylidene}[2-(morpholin-4-yl)ethyl]amine |
title_short | Crystal structure of {(E)-4-[(1-allyl-1H-1,2,3-triazol-4-yl)methoxy]benzylidene}[2-(morpholin-4-yl)ethyl]amine |
title_sort | crystal structure of {(e)-4-[(1-allyl-1h-1,2,3-triazol-4-yl)methoxy]benzylidene}[2-(morpholin-4-yl)ethyl]amine |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186139/ https://www.ncbi.nlm.nih.gov/pubmed/25309262 http://dx.doi.org/10.1107/S1600536814016754 |
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