Crystal structure of (1,3-di­methyl­thio­urea-κS)tris­(tri­phenyl­phosphane-κP)silver(I) acetate

In the mononuclear title salt, [Ag(C(3)H(8)N(2)S)(C(18)H(15)P)(3)](CH(3)COO), the Ag(I) ion exhibits a distorted tetra­hedral coordination sphere defined by three P atoms from three tri­phenyl­phosphane ligands and one S atom from a 1,3-di­­methyl­thio­urea ligand. In the crystal, the acetate anion...

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Detalles Bibliográficos
Autores principales: Wattanakanjana, Yupa, Nimthong, Arunpatcha, Darasuriyong, Chanokphat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186141/
https://www.ncbi.nlm.nih.gov/pubmed/25309189
http://dx.doi.org/10.1107/S1600536814019047
Descripción
Sumario:In the mononuclear title salt, [Ag(C(3)H(8)N(2)S)(C(18)H(15)P)(3)](CH(3)COO), the Ag(I) ion exhibits a distorted tetra­hedral coordination sphere defined by three P atoms from three tri­phenyl­phosphane ligands and one S atom from a 1,3-di­­methyl­thio­urea ligand. In the crystal, the acetate anion is linked with the complex cation via duplex N—H⋯O hydrogen bonds [graph-set motif R (2) (2)(8)].

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