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Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate
In the mononuclear title salt, [Ag(C(3)H(8)N(2)S)(C(18)H(15)P)(3)](CH(3)COO), the Ag(I) ion exhibits a distorted tetrahedral coordination sphere defined by three P atoms from three triphenylphosphane ligands and one S atom from a 1,3-dimethylthiourea ligand. In the crystal, the acetate anion...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186141/ https://www.ncbi.nlm.nih.gov/pubmed/25309189 http://dx.doi.org/10.1107/S1600536814019047 |
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author | Wattanakanjana, Yupa Nimthong, Arunpatcha Darasuriyong, Chanokphat |
author_facet | Wattanakanjana, Yupa Nimthong, Arunpatcha Darasuriyong, Chanokphat |
author_sort | Wattanakanjana, Yupa |
collection | PubMed |
description | In the mononuclear title salt, [Ag(C(3)H(8)N(2)S)(C(18)H(15)P)(3)](CH(3)COO), the Ag(I) ion exhibits a distorted tetrahedral coordination sphere defined by three P atoms from three triphenylphosphane ligands and one S atom from a 1,3-dimethylthiourea ligand. In the crystal, the acetate anion is linked with the complex cation via duplex N—H⋯O hydrogen bonds [graph-set motif R (2) (2)(8)]. |
format | Online Article Text |
id | pubmed-4186141 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41861412014-10-12 Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate Wattanakanjana, Yupa Nimthong, Arunpatcha Darasuriyong, Chanokphat Acta Crystallogr Sect E Struct Rep Online Data Reports In the mononuclear title salt, [Ag(C(3)H(8)N(2)S)(C(18)H(15)P)(3)](CH(3)COO), the Ag(I) ion exhibits a distorted tetrahedral coordination sphere defined by three P atoms from three triphenylphosphane ligands and one S atom from a 1,3-dimethylthiourea ligand. In the crystal, the acetate anion is linked with the complex cation via duplex N—H⋯O hydrogen bonds [graph-set motif R (2) (2)(8)]. International Union of Crystallography 2014-08-30 /pmc/articles/PMC4186141/ /pubmed/25309189 http://dx.doi.org/10.1107/S1600536814019047 Text en © Wattanakanjana et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Wattanakanjana, Yupa Nimthong, Arunpatcha Darasuriyong, Chanokphat Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate |
title | Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate |
title_full | Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate |
title_fullStr | Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate |
title_full_unstemmed | Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate |
title_short | Crystal structure of (1,3-dimethylthiourea-κS)tris(triphenylphosphane-κP)silver(I) acetate |
title_sort | crystal structure of (1,3-dimethylthiourea-κs)tris(triphenylphosphane-κp)silver(i) acetate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186141/ https://www.ncbi.nlm.nih.gov/pubmed/25309189 http://dx.doi.org/10.1107/S1600536814019047 |
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