Crystal structure of N-(3-benzoyl-4,5,6,7-tetra­hydro-1-benzo­thio­phen-2-yl)benzamide

In the title compound, C(22)H(19)NO(2)S, the cyclo­hexene ring adopts a half-chair conformation. The dihedral angles between the plane of the thio­phene ring and those of its amide- and carbonyl-bonded benzene rings are 7.1 (1) and 59.0 (2)°, respectively. An intra­molecular N—H⋯O hydrogen bond gene...

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Autores principales: Kaur, Manpreet, Jasinski, Jerry P., Yathirajan, H. S., Yamuna, Thammarse S., Byrappa, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186148/
https://www.ncbi.nlm.nih.gov/pubmed/25309274
http://dx.doi.org/10.1107/S1600536814016948
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author Kaur, Manpreet
Jasinski, Jerry P.
Yathirajan, H. S.
Yamuna, Thammarse S.
Byrappa, K.
author_facet Kaur, Manpreet
Jasinski, Jerry P.
Yathirajan, H. S.
Yamuna, Thammarse S.
Byrappa, K.
author_sort Kaur, Manpreet
collection PubMed
description In the title compound, C(22)H(19)NO(2)S, the cyclo­hexene ring adopts a half-chair conformation. The dihedral angles between the plane of the thio­phene ring and those of its amide- and carbonyl-bonded benzene rings are 7.1 (1) and 59.0 (2)°, respectively. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring. In the crystal, very weak aromatic π–π stacking inter­actions [centroid–centroid separation = 3.9009 (10) Å] are observed.
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spelling pubmed-41861482014-10-12 Crystal structure of N-(3-benzoyl-4,5,6,7-tetra­hydro-1-benzo­thio­phen-2-yl)benzamide Kaur, Manpreet Jasinski, Jerry P. Yathirajan, H. S. Yamuna, Thammarse S. Byrappa, K. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(22)H(19)NO(2)S, the cyclo­hexene ring adopts a half-chair conformation. The dihedral angles between the plane of the thio­phene ring and those of its amide- and carbonyl-bonded benzene rings are 7.1 (1) and 59.0 (2)°, respectively. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring. In the crystal, very weak aromatic π–π stacking inter­actions [centroid–centroid separation = 3.9009 (10) Å] are observed. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186148/ /pubmed/25309274 http://dx.doi.org/10.1107/S1600536814016948 Text en © Kaur et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kaur, Manpreet
Jasinski, Jerry P.
Yathirajan, H. S.
Yamuna, Thammarse S.
Byrappa, K.
Crystal structure of N-(3-benzoyl-4,5,6,7-tetra­hydro-1-benzo­thio­phen-2-yl)benzamide
title Crystal structure of N-(3-benzoyl-4,5,6,7-tetra­hydro-1-benzo­thio­phen-2-yl)benzamide
title_full Crystal structure of N-(3-benzoyl-4,5,6,7-tetra­hydro-1-benzo­thio­phen-2-yl)benzamide
title_fullStr Crystal structure of N-(3-benzoyl-4,5,6,7-tetra­hydro-1-benzo­thio­phen-2-yl)benzamide
title_full_unstemmed Crystal structure of N-(3-benzoyl-4,5,6,7-tetra­hydro-1-benzo­thio­phen-2-yl)benzamide
title_short Crystal structure of N-(3-benzoyl-4,5,6,7-tetra­hydro-1-benzo­thio­phen-2-yl)benzamide
title_sort crystal structure of n-(3-benzoyl-4,5,6,7-tetra­hydro-1-benzo­thio­phen-2-yl)benzamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186148/
https://www.ncbi.nlm.nih.gov/pubmed/25309274
http://dx.doi.org/10.1107/S1600536814016948
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