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Crystal structure of 3-({[(thiophen-2-yl)methylidene]hydrazinyl}carbonyl)pyridinium chloride dihydrate
In the title compound, C(11)H(10)N(3)OS(+)·Cl(−)·2H(2)O, the organic cation exhibits a dihedral angle of 21.26 (8)° between the mean planes of the pyridine and thiophene rings, and dihedral angles of 15.11 (9) and 6.49 (9)° between the mean planes of the hydrazide moiety and the pyridine and thiop...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186149/ https://www.ncbi.nlm.nih.gov/pubmed/25309289 http://dx.doi.org/10.1107/S1600536814017565 |
Sumario: | In the title compound, C(11)H(10)N(3)OS(+)·Cl(−)·2H(2)O, the organic cation exhibits a dihedral angle of 21.26 (8)° between the mean planes of the pyridine and thiophene rings, and dihedral angles of 15.11 (9) and 6.49 (9)° between the mean planes of the hydrazide moiety and the pyridine and thiophene rings, respectively. In the crystal, the organic cation, the chloride counter-anion and the two water molecules of crystallization are linked through an intricate hydrogen-bonding network consisting of O—H⋯O, O—H⋯N, N—H⋯Cl, C—H⋯Cl, C—H⋯O, N—H⋯O, O—H⋯Cl and C—H⋯S interactions that consolidate a three-dimensional network. |
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