Crystal structure of 3-({[(thio­phen-2-yl)methyl­idene]hydrazin­yl}carbon­yl)pyridinium chloride dihydrate

In the title compound, C(11)H(10)N(3)OS(+)·Cl(−)·2H(2)O, the organic cation exhibits a dihedral angle of 21.26 (8)° between the mean planes of the pyridine and thio­phene rings, and dihedral angles of 15.11 (9) and 6.49 (9)° between the mean planes of the hydrazide moiety and the pyridine and thio­p...

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Autores principales: Chandrasekaran, Thangayyah, Suresh, Mani, Josephine Novina, John, Syed Ali Padusha, Mohamed Khan, Vasuki, Gopalsamy, Kasthuri, Balasubramani
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186149/
https://www.ncbi.nlm.nih.gov/pubmed/25309289
http://dx.doi.org/10.1107/S1600536814017565
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author Chandrasekaran, Thangayyah
Suresh, Mani
Josephine Novina, John
Syed Ali Padusha, Mohamed Khan
Vasuki, Gopalsamy
Kasthuri, Balasubramani
author_facet Chandrasekaran, Thangayyah
Suresh, Mani
Josephine Novina, John
Syed Ali Padusha, Mohamed Khan
Vasuki, Gopalsamy
Kasthuri, Balasubramani
author_sort Chandrasekaran, Thangayyah
collection PubMed
description In the title compound, C(11)H(10)N(3)OS(+)·Cl(−)·2H(2)O, the organic cation exhibits a dihedral angle of 21.26 (8)° between the mean planes of the pyridine and thio­phene rings, and dihedral angles of 15.11 (9) and 6.49 (9)° between the mean planes of the hydrazide moiety and the pyridine and thio­phene rings, respectively. In the crystal, the organic cation, the chloride counter-anion and the two water mol­ecules of crystallization are linked through an intricate hydrogen-bonding network consisting of O—H⋯O, O—H⋯N, N—H⋯Cl, C—H⋯Cl, C—H⋯O, N—H⋯O, O—H⋯Cl and C—H⋯S inter­actions that consolidate a three-dimensional network.
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spelling pubmed-41861492014-10-12 Crystal structure of 3-({[(thio­phen-2-yl)methyl­idene]hydrazin­yl}carbon­yl)pyridinium chloride dihydrate Chandrasekaran, Thangayyah Suresh, Mani Josephine Novina, John Syed Ali Padusha, Mohamed Khan Vasuki, Gopalsamy Kasthuri, Balasubramani Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(11)H(10)N(3)OS(+)·Cl(−)·2H(2)O, the organic cation exhibits a dihedral angle of 21.26 (8)° between the mean planes of the pyridine and thio­phene rings, and dihedral angles of 15.11 (9) and 6.49 (9)° between the mean planes of the hydrazide moiety and the pyridine and thio­phene rings, respectively. In the crystal, the organic cation, the chloride counter-anion and the two water mol­ecules of crystallization are linked through an intricate hydrogen-bonding network consisting of O—H⋯O, O—H⋯N, N—H⋯Cl, C—H⋯Cl, C—H⋯O, N—H⋯O, O—H⋯Cl and C—H⋯S inter­actions that consolidate a three-dimensional network. International Union of Crystallography 2014-08-06 /pmc/articles/PMC4186149/ /pubmed/25309289 http://dx.doi.org/10.1107/S1600536814017565 Text en © Chandrasekaran et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Chandrasekaran, Thangayyah
Suresh, Mani
Josephine Novina, John
Syed Ali Padusha, Mohamed Khan
Vasuki, Gopalsamy
Kasthuri, Balasubramani
Crystal structure of 3-({[(thio­phen-2-yl)methyl­idene]hydrazin­yl}carbon­yl)pyridinium chloride dihydrate
title Crystal structure of 3-({[(thio­phen-2-yl)methyl­idene]hydrazin­yl}carbon­yl)pyridinium chloride dihydrate
title_full Crystal structure of 3-({[(thio­phen-2-yl)methyl­idene]hydrazin­yl}carbon­yl)pyridinium chloride dihydrate
title_fullStr Crystal structure of 3-({[(thio­phen-2-yl)methyl­idene]hydrazin­yl}carbon­yl)pyridinium chloride dihydrate
title_full_unstemmed Crystal structure of 3-({[(thio­phen-2-yl)methyl­idene]hydrazin­yl}carbon­yl)pyridinium chloride dihydrate
title_short Crystal structure of 3-({[(thio­phen-2-yl)methyl­idene]hydrazin­yl}carbon­yl)pyridinium chloride dihydrate
title_sort crystal structure of 3-({[(thio­phen-2-yl)methyl­idene]hydrazin­yl}carbon­yl)pyridinium chloride dihydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186149/
https://www.ncbi.nlm.nih.gov/pubmed/25309289
http://dx.doi.org/10.1107/S1600536814017565
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