Crystal structure of N,N′-bis­(diiso­propyl­phosphan­yl)-4-methyl­pyridine-2,6-di­amine

In the mol­ecule of the title compound, C(18)H(35)N(3)P(2), the methyl­pyridine-2,6-di­amine moiety is almost planar, with a maximum deviation of 0.0129 (9) Å for one of the amine N atoms. Whereas one of the P atoms is co-planar with this mean plane [deviation = 0.0158 (10) Å], the other P atom is c...

Descripción completa

Detalles Bibliográficos
Autores principales: Stöger, Berthold, Weil, Matthias, Bichler, Bernhard, Eder, Wolfgang, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186153/
https://www.ncbi.nlm.nih.gov/pubmed/25309237
http://dx.doi.org/10.1107/S1600536814010976
_version_ 1782338008914067456
author Stöger, Berthold
Weil, Matthias
Bichler, Bernhard
Eder, Wolfgang
Kirchner, Karl
author_facet Stöger, Berthold
Weil, Matthias
Bichler, Bernhard
Eder, Wolfgang
Kirchner, Karl
author_sort Stöger, Berthold
collection PubMed
description In the mol­ecule of the title compound, C(18)H(35)N(3)P(2), the methyl­pyridine-2,6-di­amine moiety is almost planar, with a maximum deviation of 0.0129 (9) Å for one of the amine N atoms. Whereas one of the P atoms is co-planar with this mean plane [deviation = 0.0158 (10) Å], the other P atom is considerably displaced out of the mean plane by 0.5882 (10) Å. In the crystal, no directional intermolecular interactions beyond van der Waals contacts could be identified.
format Online
Article
Text
id pubmed-4186153
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-41861532014-10-12 Crystal structure of N,N′-bis­(diiso­propyl­phosphan­yl)-4-methyl­pyridine-2,6-di­amine Stöger, Berthold Weil, Matthias Bichler, Bernhard Eder, Wolfgang Kirchner, Karl Acta Crystallogr Sect E Struct Rep Online Data Reports In the mol­ecule of the title compound, C(18)H(35)N(3)P(2), the methyl­pyridine-2,6-di­amine moiety is almost planar, with a maximum deviation of 0.0129 (9) Å for one of the amine N atoms. Whereas one of the P atoms is co-planar with this mean plane [deviation = 0.0158 (10) Å], the other P atom is considerably displaced out of the mean plane by 0.5882 (10) Å. In the crystal, no directional intermolecular interactions beyond van der Waals contacts could be identified. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186153/ /pubmed/25309237 http://dx.doi.org/10.1107/S1600536814010976 Text en © Stöger et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Stöger, Berthold
Weil, Matthias
Bichler, Bernhard
Eder, Wolfgang
Kirchner, Karl
Crystal structure of N,N′-bis­(diiso­propyl­phosphan­yl)-4-methyl­pyridine-2,6-di­amine
title Crystal structure of N,N′-bis­(diiso­propyl­phosphan­yl)-4-methyl­pyridine-2,6-di­amine
title_full Crystal structure of N,N′-bis­(diiso­propyl­phosphan­yl)-4-methyl­pyridine-2,6-di­amine
title_fullStr Crystal structure of N,N′-bis­(diiso­propyl­phosphan­yl)-4-methyl­pyridine-2,6-di­amine
title_full_unstemmed Crystal structure of N,N′-bis­(diiso­propyl­phosphan­yl)-4-methyl­pyridine-2,6-di­amine
title_short Crystal structure of N,N′-bis­(diiso­propyl­phosphan­yl)-4-methyl­pyridine-2,6-di­amine
title_sort crystal structure of n,n′-bis­(diiso­propyl­phosphan­yl)-4-methyl­pyridine-2,6-di­amine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186153/
https://www.ncbi.nlm.nih.gov/pubmed/25309237
http://dx.doi.org/10.1107/S1600536814010976
work_keys_str_mv AT stogerberthold crystalstructureofnnbisdiisopropylphosphanyl4methylpyridine26diamine
AT weilmatthias crystalstructureofnnbisdiisopropylphosphanyl4methylpyridine26diamine
AT bichlerbernhard crystalstructureofnnbisdiisopropylphosphanyl4methylpyridine26diamine
AT ederwolfgang crystalstructureofnnbisdiisopropylphosphanyl4methylpyridine26diamine
AT kirchnerkarl crystalstructureofnnbisdiisopropylphosphanyl4methylpyridine26diamine

Ejemplares similares