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Crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate

The heterocyclic molecule in the title solvate, C(16)H(14)N(4)·2CHCl(3), possesses inversion symmetry, with the inversion centre situated at the centre of the pyrazine ring. The outer pyridine rings are inclined to the central pyrazine ring by 4.89 (9)°. The compound crystallized as a chloro­form di...

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Detalles Bibliográficos
Autores principales: Schmitt, Laurette, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186168/
https://www.ncbi.nlm.nih.gov/pubmed/25309239
http://dx.doi.org/10.1107/S1600536814009544
Descripción
Sumario:The heterocyclic molecule in the title solvate, C(16)H(14)N(4)·2CHCl(3), possesses inversion symmetry, with the inversion centre situated at the centre of the pyrazine ring. The outer pyridine rings are inclined to the central pyrazine ring by 4.89 (9)°. The compound crystallized as a chloro­form disolvate with the solvent mol­ecules linked to the title mol­ecule by C—H⋯N hydrogen bonds. In the crystal, mol­ecules are further linked by π–π inter­actions involving the pyrazine and pyridine rings of neighbouring mol­ecules [inter-centroid distance = 3.5629 (12) Å; symmetry code: x, y + 1, z + 1].