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Crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate

The heterocyclic molecule in the title solvate, C(16)H(14)N(4)·2CHCl(3), possesses inversion symmetry, with the inversion centre situated at the centre of the pyrazine ring. The outer pyridine rings are inclined to the central pyrazine ring by 4.89 (9)°. The compound crystallized as a chloro­form di...

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Detalles Bibliográficos
Autores principales: Schmitt, Laurette, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186168/
https://www.ncbi.nlm.nih.gov/pubmed/25309239
http://dx.doi.org/10.1107/S1600536814009544
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author Schmitt, Laurette
Stoeckli-Evans, Helen
author_facet Schmitt, Laurette
Stoeckli-Evans, Helen
author_sort Schmitt, Laurette
collection PubMed
description The heterocyclic molecule in the title solvate, C(16)H(14)N(4)·2CHCl(3), possesses inversion symmetry, with the inversion centre situated at the centre of the pyrazine ring. The outer pyridine rings are inclined to the central pyrazine ring by 4.89 (9)°. The compound crystallized as a chloro­form disolvate with the solvent mol­ecules linked to the title mol­ecule by C—H⋯N hydrogen bonds. In the crystal, mol­ecules are further linked by π–π inter­actions involving the pyrazine and pyridine rings of neighbouring mol­ecules [inter-centroid distance = 3.5629 (12) Å; symmetry code: x, y + 1, z + 1].
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spelling pubmed-41861682014-10-12 Crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate Schmitt, Laurette Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Data Reports The heterocyclic molecule in the title solvate, C(16)H(14)N(4)·2CHCl(3), possesses inversion symmetry, with the inversion centre situated at the centre of the pyrazine ring. The outer pyridine rings are inclined to the central pyrazine ring by 4.89 (9)°. The compound crystallized as a chloro­form disolvate with the solvent mol­ecules linked to the title mol­ecule by C—H⋯N hydrogen bonds. In the crystal, mol­ecules are further linked by π–π inter­actions involving the pyrazine and pyridine rings of neighbouring mol­ecules [inter-centroid distance = 3.5629 (12) Å; symmetry code: x, y + 1, z + 1]. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186168/ /pubmed/25309239 http://dx.doi.org/10.1107/S1600536814009544 Text en © Schmitt and Stoeckli-Evans 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Schmitt, Laurette
Stoeckli-Evans, Helen
Crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate
title Crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate
title_full Crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate
title_fullStr Crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate
title_full_unstemmed Crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate
title_short Crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate
title_sort crystal structure of 2,5-bis­(4-methyl­pyridin-2-yl)pyrazine chloro­form disolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186168/
https://www.ncbi.nlm.nih.gov/pubmed/25309239
http://dx.doi.org/10.1107/S1600536814009544
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