Cargando…
Crystal structure of 2,5-bis(4-methylpyridin-2-yl)pyrazine chloroform disolvate
The heterocyclic molecule in the title solvate, C(16)H(14)N(4)·2CHCl(3), possesses inversion symmetry, with the inversion centre situated at the centre of the pyrazine ring. The outer pyridine rings are inclined to the central pyrazine ring by 4.89 (9)°. The compound crystallized as a chloroform di...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186168/ https://www.ncbi.nlm.nih.gov/pubmed/25309239 http://dx.doi.org/10.1107/S1600536814009544 |
_version_ | 1782338012367028224 |
---|---|
author | Schmitt, Laurette Stoeckli-Evans, Helen |
author_facet | Schmitt, Laurette Stoeckli-Evans, Helen |
author_sort | Schmitt, Laurette |
collection | PubMed |
description | The heterocyclic molecule in the title solvate, C(16)H(14)N(4)·2CHCl(3), possesses inversion symmetry, with the inversion centre situated at the centre of the pyrazine ring. The outer pyridine rings are inclined to the central pyrazine ring by 4.89 (9)°. The compound crystallized as a chloroform disolvate with the solvent molecules linked to the title molecule by C—H⋯N hydrogen bonds. In the crystal, molecules are further linked by π–π interactions involving the pyrazine and pyridine rings of neighbouring molecules [inter-centroid distance = 3.5629 (12) Å; symmetry code: x, y + 1, z + 1]. |
format | Online Article Text |
id | pubmed-4186168 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41861682014-10-12 Crystal structure of 2,5-bis(4-methylpyridin-2-yl)pyrazine chloroform disolvate Schmitt, Laurette Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Data Reports The heterocyclic molecule in the title solvate, C(16)H(14)N(4)·2CHCl(3), possesses inversion symmetry, with the inversion centre situated at the centre of the pyrazine ring. The outer pyridine rings are inclined to the central pyrazine ring by 4.89 (9)°. The compound crystallized as a chloroform disolvate with the solvent molecules linked to the title molecule by C—H⋯N hydrogen bonds. In the crystal, molecules are further linked by π–π interactions involving the pyrazine and pyridine rings of neighbouring molecules [inter-centroid distance = 3.5629 (12) Å; symmetry code: x, y + 1, z + 1]. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186168/ /pubmed/25309239 http://dx.doi.org/10.1107/S1600536814009544 Text en © Schmitt and Stoeckli-Evans 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Schmitt, Laurette Stoeckli-Evans, Helen Crystal structure of 2,5-bis(4-methylpyridin-2-yl)pyrazine chloroform disolvate |
title | Crystal structure of 2,5-bis(4-methylpyridin-2-yl)pyrazine chloroform disolvate
|
title_full | Crystal structure of 2,5-bis(4-methylpyridin-2-yl)pyrazine chloroform disolvate
|
title_fullStr | Crystal structure of 2,5-bis(4-methylpyridin-2-yl)pyrazine chloroform disolvate
|
title_full_unstemmed | Crystal structure of 2,5-bis(4-methylpyridin-2-yl)pyrazine chloroform disolvate
|
title_short | Crystal structure of 2,5-bis(4-methylpyridin-2-yl)pyrazine chloroform disolvate
|
title_sort | crystal structure of 2,5-bis(4-methylpyridin-2-yl)pyrazine chloroform disolvate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186168/ https://www.ncbi.nlm.nih.gov/pubmed/25309239 http://dx.doi.org/10.1107/S1600536814009544 |
work_keys_str_mv | AT schmittlaurette crystalstructureof25bis4methylpyridin2ylpyrazinechloroformdisolvate AT stoecklievanshelen crystalstructureof25bis4methylpyridin2ylpyrazinechloroformdisolvate |