Crystal structure of 4-chloro-2-iodo­aniline

In the crystal structure of the title compound, C(6)H(5)ClIN, the amino group engages in N—H⋯N hydrogen bonding, creating [100] chains. A Cl⋯I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring mol­ecules reveal highly offset π-stacking characterized by a centroid–centroid dista...

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Detalles Bibliográficos
Autores principales: Quinn, Taylor R., Tanski, Joseph M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186172/
https://www.ncbi.nlm.nih.gov/pubmed/25309269
http://dx.doi.org/10.1107/S1600536814016869
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author Quinn, Taylor R.
Tanski, Joseph M.
author_facet Quinn, Taylor R.
Tanski, Joseph M.
author_sort Quinn, Taylor R.
collection PubMed
description In the crystal structure of the title compound, C(6)H(5)ClIN, the amino group engages in N—H⋯N hydrogen bonding, creating [100] chains. A Cl⋯I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring mol­ecules reveal highly offset π-stacking characterized by a centroid–centroid distance of 4.154 (1), a centroid-to-plane distance of 3.553 (3) and ring-offset slippage of 2.151 (6) Å.
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spelling pubmed-41861722014-10-12 Crystal structure of 4-chloro-2-iodo­aniline Quinn, Taylor R. Tanski, Joseph M. Acta Crystallogr Sect E Struct Rep Online Data Reports In the crystal structure of the title compound, C(6)H(5)ClIN, the amino group engages in N—H⋯N hydrogen bonding, creating [100] chains. A Cl⋯I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring mol­ecules reveal highly offset π-stacking characterized by a centroid–centroid distance of 4.154 (1), a centroid-to-plane distance of 3.553 (3) and ring-offset slippage of 2.151 (6) Å. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186172/ /pubmed/25309269 http://dx.doi.org/10.1107/S1600536814016869 Text en © Quinn and Tanski 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Quinn, Taylor R.
Tanski, Joseph M.
Crystal structure of 4-chloro-2-iodo­aniline
title Crystal structure of 4-chloro-2-iodo­aniline
title_full Crystal structure of 4-chloro-2-iodo­aniline
title_fullStr Crystal structure of 4-chloro-2-iodo­aniline
title_full_unstemmed Crystal structure of 4-chloro-2-iodo­aniline
title_short Crystal structure of 4-chloro-2-iodo­aniline
title_sort crystal structure of 4-chloro-2-iodo­aniline
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186172/
https://www.ncbi.nlm.nih.gov/pubmed/25309269
http://dx.doi.org/10.1107/S1600536814016869
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