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Crystal structure of 4-fluoro-N-[2-(4-fluoro­benzo­yl)hydra­zine-1-carbono­thio­yl]benzamide

In the title compound, C(15)H(11)F(2)N(3)O(2)S, the dihedral angle between the fluoro­benzene rings is 88.43 (10)° and that between the central semithiocarbazide grouping is 47.00 (11)°. The dihedral angle between the amide group and attached fluoro­benzene ring is 50.52 (11)°; the equivalent angle...

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Autores principales: Firdausiah, Syadza, Salleh Huddin, Ameera Aqeela, Hasbullah, Siti Aishah, Yamin, Bohari M., Yusoff, Siti Fairus M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186173/
https://www.ncbi.nlm.nih.gov/pubmed/25309250
http://dx.doi.org/10.1107/S1600536814015761
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author Firdausiah, Syadza
Salleh Huddin, Ameera Aqeela
Hasbullah, Siti Aishah
Yamin, Bohari M.
Yusoff, Siti Fairus M.
author_facet Firdausiah, Syadza
Salleh Huddin, Ameera Aqeela
Hasbullah, Siti Aishah
Yamin, Bohari M.
Yusoff, Siti Fairus M.
author_sort Firdausiah, Syadza
collection PubMed
description In the title compound, C(15)H(11)F(2)N(3)O(2)S, the dihedral angle between the fluoro­benzene rings is 88.43 (10)° and that between the central semithiocarbazide grouping is 47.00 (11)°. The dihedral angle between the amide group and attached fluoro­benzene ring is 50.52 (11)°; the equivalent angle between the carbonyl­thio­amide group and its attached ring is 12.98 (10)°. The major twists in the mol­ecule occur about the C—N—N—C bonds [torsion angle = −138.7 (2)°] and the C(ar)—C(ar)—C—N (ar = aromatic) bonds [−132.0 (2)°]. An intra­molecular N—H⋯O hydrogen bond occurs, which generates an S(6) ring. In the crystal, the mol­ecules are linked by N—H⋯O and N—H⋯S hydrogen bonds, generating (001) sheets. Weak C—H⋯O and C—H⋯F inter­actions are also observed.
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spelling pubmed-41861732014-10-12 Crystal structure of 4-fluoro-N-[2-(4-fluoro­benzo­yl)hydra­zine-1-carbono­thio­yl]benzamide Firdausiah, Syadza Salleh Huddin, Ameera Aqeela Hasbullah, Siti Aishah Yamin, Bohari M. Yusoff, Siti Fairus M. Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(15)H(11)F(2)N(3)O(2)S, the dihedral angle between the fluoro­benzene rings is 88.43 (10)° and that between the central semithiocarbazide grouping is 47.00 (11)°. The dihedral angle between the amide group and attached fluoro­benzene ring is 50.52 (11)°; the equivalent angle between the carbonyl­thio­amide group and its attached ring is 12.98 (10)°. The major twists in the mol­ecule occur about the C—N—N—C bonds [torsion angle = −138.7 (2)°] and the C(ar)—C(ar)—C—N (ar = aromatic) bonds [−132.0 (2)°]. An intra­molecular N—H⋯O hydrogen bond occurs, which generates an S(6) ring. In the crystal, the mol­ecules are linked by N—H⋯O and N—H⋯S hydrogen bonds, generating (001) sheets. Weak C—H⋯O and C—H⋯F inter­actions are also observed. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186173/ /pubmed/25309250 http://dx.doi.org/10.1107/S1600536814015761 Text en © Firdausiah et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Firdausiah, Syadza
Salleh Huddin, Ameera Aqeela
Hasbullah, Siti Aishah
Yamin, Bohari M.
Yusoff, Siti Fairus M.
Crystal structure of 4-fluoro-N-[2-(4-fluoro­benzo­yl)hydra­zine-1-carbono­thio­yl]benzamide
title Crystal structure of 4-fluoro-N-[2-(4-fluoro­benzo­yl)hydra­zine-1-carbono­thio­yl]benzamide
title_full Crystal structure of 4-fluoro-N-[2-(4-fluoro­benzo­yl)hydra­zine-1-carbono­thio­yl]benzamide
title_fullStr Crystal structure of 4-fluoro-N-[2-(4-fluoro­benzo­yl)hydra­zine-1-carbono­thio­yl]benzamide
title_full_unstemmed Crystal structure of 4-fluoro-N-[2-(4-fluoro­benzo­yl)hydra­zine-1-carbono­thio­yl]benzamide
title_short Crystal structure of 4-fluoro-N-[2-(4-fluoro­benzo­yl)hydra­zine-1-carbono­thio­yl]benzamide
title_sort crystal structure of 4-fluoro-n-[2-(4-fluoro­benzo­yl)hydra­zine-1-carbono­thio­yl]benzamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186173/
https://www.ncbi.nlm.nih.gov/pubmed/25309250
http://dx.doi.org/10.1107/S1600536814015761
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