Crystal structure of poly[{μ-N,N′-bis[(pyridin-4-yl)meth­yl]oxalamide}-μ-oxalato-cobalt(II)]

In the polymeric title compound, [Co(C(2)O(4))(C(14)H(14)N(4)O(2))](n), the Co(II) atom is six-coordinated by two N atoms from symmetry-related bis­[(pyridin-4-yl)meth­yl]oxalamide (BPMO) ligands and four O atoms from two centrosymmetric oxalate anions in a distorted octa­hedral coordination geometr...

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Detalles Bibliográficos
Autores principales: Zou, Hengye, Qi, Yanjuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186178/
https://www.ncbi.nlm.nih.gov/pubmed/25309173
http://dx.doi.org/10.1107/S1600536814015608
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author Zou, Hengye
Qi, Yanjuan
author_facet Zou, Hengye
Qi, Yanjuan
author_sort Zou, Hengye
collection PubMed
description In the polymeric title compound, [Co(C(2)O(4))(C(14)H(14)N(4)O(2))](n), the Co(II) atom is six-coordinated by two N atoms from symmetry-related bis­[(pyridin-4-yl)meth­yl]oxalamide (BPMO) ligands and four O atoms from two centrosymmetric oxalate anions in a distorted octa­hedral coordination geometry. The Co(II) atoms are linked by the oxalate anions into a chain running parallel to [100]. The chains are linked by the BPMO ligands into a three-dimensional architecture. In addition, N—H⋯O hydrogen bonds stabilize the crystal packing.
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spelling pubmed-41861782014-10-12 Crystal structure of poly[{μ-N,N′-bis[(pyridin-4-yl)meth­yl]oxalamide}-μ-oxalato-cobalt(II)] Zou, Hengye Qi, Yanjuan Acta Crystallogr Sect E Struct Rep Online Data Reports In the polymeric title compound, [Co(C(2)O(4))(C(14)H(14)N(4)O(2))](n), the Co(II) atom is six-coordinated by two N atoms from symmetry-related bis­[(pyridin-4-yl)meth­yl]oxalamide (BPMO) ligands and four O atoms from two centrosymmetric oxalate anions in a distorted octa­hedral coordination geometry. The Co(II) atoms are linked by the oxalate anions into a chain running parallel to [100]. The chains are linked by the BPMO ligands into a three-dimensional architecture. In addition, N—H⋯O hydrogen bonds stabilize the crystal packing. International Union of Crystallography 2014-08-01 /pmc/articles/PMC4186178/ /pubmed/25309173 http://dx.doi.org/10.1107/S1600536814015608 Text en © Zou and Qi 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Zou, Hengye
Qi, Yanjuan
Crystal structure of poly[{μ-N,N′-bis[(pyridin-4-yl)meth­yl]oxalamide}-μ-oxalato-cobalt(II)]
title Crystal structure of poly[{μ-N,N′-bis[(pyridin-4-yl)meth­yl]oxalamide}-μ-oxalato-cobalt(II)]
title_full Crystal structure of poly[{μ-N,N′-bis[(pyridin-4-yl)meth­yl]oxalamide}-μ-oxalato-cobalt(II)]
title_fullStr Crystal structure of poly[{μ-N,N′-bis[(pyridin-4-yl)meth­yl]oxalamide}-μ-oxalato-cobalt(II)]
title_full_unstemmed Crystal structure of poly[{μ-N,N′-bis[(pyridin-4-yl)meth­yl]oxalamide}-μ-oxalato-cobalt(II)]
title_short Crystal structure of poly[{μ-N,N′-bis[(pyridin-4-yl)meth­yl]oxalamide}-μ-oxalato-cobalt(II)]
title_sort crystal structure of poly[{μ-n,n′-bis[(pyridin-4-yl)meth­yl]oxalamide}-μ-oxalato-cobalt(ii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186178/
https://www.ncbi.nlm.nih.gov/pubmed/25309173
http://dx.doi.org/10.1107/S1600536814015608
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