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Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-trimethylethane-1,2-diamine-κ(2) N,N′)dichloridomercury(II)
In the structure of the title compound, [HgCl(2)(C(12)H(20)N(2))], the Hg(II) atom has a distorted tetrahedral coordination sphere defined by two tertiary amine N-atom donors, as well as two Cl(−) anions [the dihedral angle between the N—Hg—N and Cl—Hg—Cl planes is 82.80 (9)°]. The five-membered ch...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186188/ https://www.ncbi.nlm.nih.gov/pubmed/25309156 http://dx.doi.org/10.1107/S1600536814017516 |
Sumario: | In the structure of the title compound, [HgCl(2)(C(12)H(20)N(2))], the Hg(II) atom has a distorted tetrahedral coordination sphere defined by two tertiary amine N-atom donors, as well as two Cl(−) anions [the dihedral angle between the N—Hg—N and Cl—Hg—Cl planes is 82.80 (9)°]. The five-membered chelate ring adopts an envelope conformation, with puckering parameters of Q(2) = 0.446 (6) Å and ϕ(2) = 88.8 (6)°, with the two amine CH(3) substituents on opposite sides of the ring. In the crystal, the molecules are linked by C—H⋯Cl interactions into a zigzag chain parallel to [101]. |
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