Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-tri­methyl­ethane-1,2-di­amine-κ(2) N,N′)di­chloridomercury(II)

In the structure of the title compound, [HgCl(2)(C(12)H(20)N(2))], the Hg(II) atom has a distorted tetra­hedral coordination sphere defined by two tertiary amine N-atom donors, as well as two Cl(−) anions [the dihedral angle between the N—Hg—N and Cl—Hg—Cl planes is 82.80 (9)°]. The five-membered ch...

Descripción completa

Detalles Bibliográficos
Autores principales: Manjare, Sudesh T., Singh, Harkesh B., Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186188/
https://www.ncbi.nlm.nih.gov/pubmed/25309156
http://dx.doi.org/10.1107/S1600536814017516
_version_ 1782338017122320384
author Manjare, Sudesh T.
Singh, Harkesh B.
Butcher, Ray J.
author_facet Manjare, Sudesh T.
Singh, Harkesh B.
Butcher, Ray J.
author_sort Manjare, Sudesh T.
collection PubMed
description In the structure of the title compound, [HgCl(2)(C(12)H(20)N(2))], the Hg(II) atom has a distorted tetra­hedral coordination sphere defined by two tertiary amine N-atom donors, as well as two Cl(−) anions [the dihedral angle between the N—Hg—N and Cl—Hg—Cl planes is 82.80 (9)°]. The five-membered chelate ring adopts an envelope conformation, with puckering parameters of Q(2) = 0.446 (6) Å and ϕ(2) = 88.8 (6)°, with the two amine CH(3) substituents on opposite sides of the ring. In the crystal, the mol­ecules are linked by C—H⋯Cl inter­actions into a zigzag chain parallel to [101].
format Online
Article
Text
id pubmed-4186188
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-41861882014-10-12 Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-tri­methyl­ethane-1,2-di­amine-κ(2) N,N′)di­chloridomercury(II) Manjare, Sudesh T. Singh, Harkesh B. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Research Communications In the structure of the title compound, [HgCl(2)(C(12)H(20)N(2))], the Hg(II) atom has a distorted tetra­hedral coordination sphere defined by two tertiary amine N-atom donors, as well as two Cl(−) anions [the dihedral angle between the N—Hg—N and Cl—Hg—Cl planes is 82.80 (9)°]. The five-membered chelate ring adopts an envelope conformation, with puckering parameters of Q(2) = 0.446 (6) Å and ϕ(2) = 88.8 (6)°, with the two amine CH(3) substituents on opposite sides of the ring. In the crystal, the mol­ecules are linked by C—H⋯Cl inter­actions into a zigzag chain parallel to [101]. International Union of Crystallography 2014-08-06 /pmc/articles/PMC4186188/ /pubmed/25309156 http://dx.doi.org/10.1107/S1600536814017516 Text en © Manjare et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Manjare, Sudesh T.
Singh, Harkesh B.
Butcher, Ray J.
Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-tri­methyl­ethane-1,2-di­amine-κ(2) N,N′)di­chloridomercury(II)
title Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-tri­methyl­ethane-1,2-di­amine-κ(2) N,N′)di­chloridomercury(II)
title_full Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-tri­methyl­ethane-1,2-di­amine-κ(2) N,N′)di­chloridomercury(II)
title_fullStr Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-tri­methyl­ethane-1,2-di­amine-κ(2) N,N′)di­chloridomercury(II)
title_full_unstemmed Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-tri­methyl­ethane-1,2-di­amine-κ(2) N,N′)di­chloridomercury(II)
title_short Crystal structure of (N (1)-benzyl-N (1),N (2),N (2)-tri­methyl­ethane-1,2-di­amine-κ(2) N,N′)di­chloridomercury(II)
title_sort crystal structure of (n (1)-benzyl-n (1),n (2),n (2)-tri­methyl­ethane-1,2-di­amine-κ(2) n,n′)di­chloridomercury(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186188/
https://www.ncbi.nlm.nih.gov/pubmed/25309156
http://dx.doi.org/10.1107/S1600536814017516
work_keys_str_mv AT manjaresudesht crystalstructureofn1benzyln1n2n2trimethylethane12diaminek2nndichloridomercuryii
AT singhharkeshb crystalstructureofn1benzyln1n2n2trimethylethane12diaminek2nndichloridomercuryii
AT butcherrayj crystalstructureofn1benzyln1n2n2trimethylethane12diaminek2nndichloridomercuryii

Ejemplares similares