Crystal structure of tetra­kis­(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(2-methyl­benzo­nitrile-κN)rhodium(II)](Rh—Rh)

The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(C(8)H(7)N)(2)], exhibits inversion symmetry. The four acetamidate ligands bridging the dirhodium core are arranged in a 2,2-trans manner with two N atoms and two O atoms coordinating to each Rh(II) atom trans to one another. T...

Descripción completa

Detalles Bibliográficos
Autores principales: Eagle, Cassandra T., Atem-Tambe, Nkongho, Kpogo, Kenneth K., Tan, Jennie, Cook, Kevin M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186189/
https://www.ncbi.nlm.nih.gov/pubmed/25309187
http://dx.doi.org/10.1107/S1600536814017930
_version_ 1782338017366638592
author Eagle, Cassandra T.
Atem-Tambe, Nkongho
Kpogo, Kenneth K.
Tan, Jennie
Cook, Kevin M.
author_facet Eagle, Cassandra T.
Atem-Tambe, Nkongho
Kpogo, Kenneth K.
Tan, Jennie
Cook, Kevin M.
author_sort Eagle, Cassandra T.
collection PubMed
description The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(C(8)H(7)N)(2)], exhibits inversion symmetry. The four acetamidate ligands bridging the dirhodium core are arranged in a 2,2-trans manner with two N atoms and two O atoms coordinating to each Rh(II) atom trans to one another. The N(eq)—Rh—Rh—O(eq) torsion angles on the acetamidate bridge vary between −4.07 (5) and −6.78 (7)°. The axial nitrile ligands complete the distorted octa­hedral coordination sphere of each Rh(II) atom and show a nonlinear coordination with Rh—N—C bond angles of 151.6 (3) and 152.5 (3)°. The bond lengths of the two nitrile triple bonds are 1.133 (5) and 1.137 (5) Å.
format Online
Article
Text
id pubmed-4186189
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-41861892014-10-12 Crystal structure of tetra­kis­(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(2-methyl­benzo­nitrile-κN)rhodium(II)](Rh—Rh) Eagle, Cassandra T. Atem-Tambe, Nkongho Kpogo, Kenneth K. Tan, Jennie Cook, Kevin M. Acta Crystallogr Sect E Struct Rep Online Data Reports The complex molecule of the title compound, [Rh(2){N(C(6)H(5))COCH(3)}(4)(C(8)H(7)N)(2)], exhibits inversion symmetry. The four acetamidate ligands bridging the dirhodium core are arranged in a 2,2-trans manner with two N atoms and two O atoms coordinating to each Rh(II) atom trans to one another. The N(eq)—Rh—Rh—O(eq) torsion angles on the acetamidate bridge vary between −4.07 (5) and −6.78 (7)°. The axial nitrile ligands complete the distorted octa­hedral coordination sphere of each Rh(II) atom and show a nonlinear coordination with Rh—N—C bond angles of 151.6 (3) and 152.5 (3)°. The bond lengths of the two nitrile triple bonds are 1.133 (5) and 1.137 (5) Å. International Union of Crystallography 2014-08-20 /pmc/articles/PMC4186189/ /pubmed/25309187 http://dx.doi.org/10.1107/S1600536814017930 Text en © Eagle et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Eagle, Cassandra T.
Atem-Tambe, Nkongho
Kpogo, Kenneth K.
Tan, Jennie
Cook, Kevin M.
Crystal structure of tetra­kis­(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(2-methyl­benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title Crystal structure of tetra­kis­(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(2-methyl­benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_full Crystal structure of tetra­kis­(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(2-methyl­benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_fullStr Crystal structure of tetra­kis­(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(2-methyl­benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_full_unstemmed Crystal structure of tetra­kis­(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(2-methyl­benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_short Crystal structure of tetra­kis­(μ-N-phenyl­acetamidato)-κ(4) N:O;κ(4) O:N-bis­[(2-methyl­benzo­nitrile-κN)rhodium(II)](Rh—Rh)
title_sort crystal structure of tetra­kis­(μ-n-phenyl­acetamidato)-κ(4) n:o;κ(4) o:n-bis­[(2-methyl­benzo­nitrile-κn)rhodium(ii)](rh—rh)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186189/
https://www.ncbi.nlm.nih.gov/pubmed/25309187
http://dx.doi.org/10.1107/S1600536814017930
work_keys_str_mv AT eaglecassandrat crystalstructureoftetrakismnphenylacetamidatok4nok4onbis2methylbenzonitrileknrhodiumiirhrh
AT atemtambenkongho crystalstructureoftetrakismnphenylacetamidatok4nok4onbis2methylbenzonitrileknrhodiumiirhrh
AT kpogokennethk crystalstructureoftetrakismnphenylacetamidatok4nok4onbis2methylbenzonitrileknrhodiumiirhrh
AT tanjennie crystalstructureoftetrakismnphenylacetamidatok4nok4onbis2methylbenzonitrileknrhodiumiirhrh
AT cookkevinm crystalstructureoftetrakismnphenylacetamidatok4nok4onbis2methylbenzonitrileknrhodiumiirhrh

Ejemplares similares