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Crystal structure of 1-cyclo­propane­carbon­yl-3-methyl-2,6-di-p-tolyl­piperidin-4-one

The title compound, C(24)H(27)NO(2), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules have very similar conformations and each exhibits an intra­molecular C—H⋯π inter­action. The central piperidine rings adopt boat conformations and the p-tolyl rings...

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Detalles Bibliográficos
Autores principales: Kamaraj, A., Ranjith, S., Rajkumar, R., Mohanraj, G., Krishnasamy, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186191/
https://www.ncbi.nlm.nih.gov/pubmed/25309223
http://dx.doi.org/10.1107/S1600536814018546
Descripción
Sumario:The title compound, C(24)H(27)NO(2), crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules have very similar conformations and each exhibits an intra­molecular C—H⋯π inter­action. The central piperidine rings adopt boat conformations and the p-tolyl rings are inclined to the mean plane of the piperidine ring by 71.21 (11) and 89.86 (12)° in mol­ecule A and by 68.01 (12) and 89.33 (12)° in mol­ecule B. The cyclopropanecarbonyl group is oriented at an angle of 68.5 (2)° with respect to the mean plane of the piperidine ring in mol­ecule A and 66.2 (2)° in mol­ecule B. In the crystal, the A and B mol­ecules are linked by C—H⋯O hydrogen bonds, enclosing R (2) (1)(6) ring motifs, forming ribbons running along the a-axis direction.