Crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate

In the title compound, C(17)H(21)N(2)O(6)P·CH(3)OH, the planes of the 4-nitro­aniline and 2-hy­droxy­phenyl groups form a dihedral angle of 84.04 (8)°. The P atom exhibits tetra­hedral geometry involving two O-ethyl groups, a Cα atom and a double-bonded O atom. In the crystal, O—H⋯O, N—H⋯O and C—H⋯O...

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Detalles Bibliográficos
Autores principales: Wang, QingMing, Su, Feng, Yang, TingTing, Lu, LiPing, Zhu, MiaoLi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186192/
https://www.ncbi.nlm.nih.gov/pubmed/25309221
http://dx.doi.org/10.1107/S1600536814018649
Descripción
Sumario:In the title compound, C(17)H(21)N(2)O(6)P·CH(3)OH, the planes of the 4-nitro­aniline and 2-hy­droxy­phenyl groups form a dihedral angle of 84.04 (8)°. The P atom exhibits tetra­hedral geometry involving two O-ethyl groups, a Cα atom and a double-bonded O atom. In the crystal, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the α-amino­phospho­nic acid and methanol mol­ecules into chains that propagate parallel to the a axis.

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