Crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate

In the title compound, C(17)H(21)N(2)O(6)P·CH(3)OH, the planes of the 4-nitro­aniline and 2-hy­droxy­phenyl groups form a dihedral angle of 84.04 (8)°. The P atom exhibits tetra­hedral geometry involving two O-ethyl groups, a Cα atom and a double-bonded O atom. In the crystal, O—H⋯O, N—H⋯O and C—H⋯O...

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Detalles Bibliográficos
Autores principales: Wang, QingMing, Su, Feng, Yang, TingTing, Lu, LiPing, Zhu, MiaoLi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186192/
https://www.ncbi.nlm.nih.gov/pubmed/25309221
http://dx.doi.org/10.1107/S1600536814018649
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author Wang, QingMing
Su, Feng
Yang, TingTing
Lu, LiPing
Zhu, MiaoLi
author_facet Wang, QingMing
Su, Feng
Yang, TingTing
Lu, LiPing
Zhu, MiaoLi
author_sort Wang, QingMing
collection PubMed
description In the title compound, C(17)H(21)N(2)O(6)P·CH(3)OH, the planes of the 4-nitro­aniline and 2-hy­droxy­phenyl groups form a dihedral angle of 84.04 (8)°. The P atom exhibits tetra­hedral geometry involving two O-ethyl groups, a Cα atom and a double-bonded O atom. In the crystal, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the α-amino­phospho­nic acid and methanol mol­ecules into chains that propagate parallel to the a axis.
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spelling pubmed-41861922014-10-12 Crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate Wang, QingMing Su, Feng Yang, TingTing Lu, LiPing Zhu, MiaoLi Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(17)H(21)N(2)O(6)P·CH(3)OH, the planes of the 4-nitro­aniline and 2-hy­droxy­phenyl groups form a dihedral angle of 84.04 (8)°. The P atom exhibits tetra­hedral geometry involving two O-ethyl groups, a Cα atom and a double-bonded O atom. In the crystal, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the α-amino­phospho­nic acid and methanol mol­ecules into chains that propagate parallel to the a axis. International Union of Crystallography 2014-08-30 /pmc/articles/PMC4186192/ /pubmed/25309221 http://dx.doi.org/10.1107/S1600536814018649 Text en © Wang et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Wang, QingMing
Su, Feng
Yang, TingTing
Lu, LiPing
Zhu, MiaoLi
Crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate
title Crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate
title_full Crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate
title_fullStr Crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate
title_full_unstemmed Crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate
title_short Crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate
title_sort crystal structure of diethyl [(4-nitro­phenyl­amino)(2-hy­droxy­phen­yl)meth­yl]phospho­nate methanol monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186192/
https://www.ncbi.nlm.nih.gov/pubmed/25309221
http://dx.doi.org/10.1107/S1600536814018649
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