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Crystal structure of 2-[(E)-4-benz­yloxy-2-hy­droxy­benzyl­idene]-N-cyclo­hexyl­hydrazinecarbo­thio­amide aceto­nitrile hemisolvate

The asymmetric unit of the title compound, C(21)H(25)N(3)O(2)S·0.5C(2)H(3)N, contains two independent mol­ecules with almost similar structural properties along with a solvent mol­ecule of aceto­nitrile. The compound exists in the E conformation with respect to the azomethine C=N double bond. The hy...

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Detalles Bibliográficos
Autores principales: Sajitha, N. R., Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186196/
https://www.ncbi.nlm.nih.gov/pubmed/25309295
http://dx.doi.org/10.1107/S1600536814017905
Descripción
Sumario:The asymmetric unit of the title compound, C(21)H(25)N(3)O(2)S·0.5C(2)H(3)N, contains two independent mol­ecules with almost similar structural properties along with a solvent mol­ecule of aceto­nitrile. The compound exists in the E conformation with respect to the azomethine C=N double bond. The hydrazinecarbo­thio­amide moieties in both independent mol­ecules are almost planar [maximum deviations of 0.013 (2) and 0.007 (2) Å]. The mol­ecular conformation is stabilized in each case by an intra­molecular N—H⋯N hydrogen bond. In the crystal, pairs of N—H⋯S hydrogen bonds link each of the independent mol­ecules into inversion dimers. The dimers are inter­connected by means of three C—H⋯π inter­actions.