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Crystal structure of 2-[(E)-4-benzyloxy-2-hydroxybenzylidene]-N-cyclohexylhydrazinecarbothioamide acetonitrile hemisolvate
The asymmetric unit of the title compound, C(21)H(25)N(3)O(2)S·0.5C(2)H(3)N, contains two independent molecules with almost similar structural properties along with a solvent molecule of acetonitrile. The compound exists in the E conformation with respect to the azomethine C=N double bond. The hy...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186196/ https://www.ncbi.nlm.nih.gov/pubmed/25309295 http://dx.doi.org/10.1107/S1600536814017905 |
Sumario: | The asymmetric unit of the title compound, C(21)H(25)N(3)O(2)S·0.5C(2)H(3)N, contains two independent molecules with almost similar structural properties along with a solvent molecule of acetonitrile. The compound exists in the E conformation with respect to the azomethine C=N double bond. The hydrazinecarbothioamide moieties in both independent molecules are almost planar [maximum deviations of 0.013 (2) and 0.007 (2) Å]. The molecular conformation is stabilized in each case by an intramolecular N—H⋯N hydrogen bond. In the crystal, pairs of N—H⋯S hydrogen bonds link each of the independent molecules into inversion dimers. The dimers are interconnected by means of three C—H⋯π interactions. |
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