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Crystal structure of 2-cyano-N′-(cyclo­hexyl­idene)acetohydrazide

In the title compound, C(9)H(13)N(3)O, the cyclo­hexyl­idene ring adopts a chair conformation and the bond-angle sum at the C atom linked to the N atom is 359.6°. The cyano­acetohydrazide grouping is close to planar (r.m.s. deviation for the non-H atoms = 0.031 Å) and subtends a dihedral angle of 64...

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Detalles Bibliográficos
Autores principales: Harrison, William T. A., Al-Sakka, Ola K., Fleita, Daisy H., Saleh, Amina, Salem, Sara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186197/
https://www.ncbi.nlm.nih.gov/pubmed/25309235
http://dx.doi.org/10.1107/S1600536814009350
Descripción
Sumario:In the title compound, C(9)H(13)N(3)O, the cyclo­hexyl­idene ring adopts a chair conformation and the bond-angle sum at the C atom linked to the N atom is 359.6°. The cyano­acetohydrazide grouping is close to planar (r.m.s. deviation for the non-H atoms = 0.031 Å) and subtends a dihedral angle of 64.08 (4)° with the four C atoms forming the seat of the chair. The C=O and N—H groups are in a syn conformation (O—C—N—H = −5°). In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops; this dimer linkage is reinforced by a pair of C—H⋯O inter­actions, which generate R (2) (2)(14) loops. The dimers are linked by C—H⋯N(c) (c = cyanide) inter­actions into [100] ladders, which feature C(4) chains and R (4) (4)(20) loops.