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Crystal structure of 2-cyano-N′-(cyclohexylidene)acetohydrazide
In the title compound, C(9)H(13)N(3)O, the cyclohexylidene ring adopts a chair conformation and the bond-angle sum at the C atom linked to the N atom is 359.6°. The cyanoacetohydrazide grouping is close to planar (r.m.s. deviation for the non-H atoms = 0.031 Å) and subtends a dihedral angle of 64...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186197/ https://www.ncbi.nlm.nih.gov/pubmed/25309235 http://dx.doi.org/10.1107/S1600536814009350 |
Sumario: | In the title compound, C(9)H(13)N(3)O, the cyclohexylidene ring adopts a chair conformation and the bond-angle sum at the C atom linked to the N atom is 359.6°. The cyanoacetohydrazide grouping is close to planar (r.m.s. deviation for the non-H atoms = 0.031 Å) and subtends a dihedral angle of 64.08 (4)° with the four C atoms forming the seat of the chair. The C=O and N—H groups are in a syn conformation (O—C—N—H = −5°). In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops; this dimer linkage is reinforced by a pair of C—H⋯O interactions, which generate R (2) (2)(14) loops. The dimers are linked by C—H⋯N(c) (c = cyanide) interactions into [100] ladders, which feature C(4) chains and R (4) (4)(20) loops. |
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