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Reduced chemically modified graphene oxide for supercapacitor electrode
An efficient active material for supercapacitor electrodes is prepared by reacting potassium hydroxide (KOH) with graphene oxide followed by chemical reduction with hydrazine. The electrochemical performance of KOH treated graphene oxide reduced for 24 h (reduced chemically modified graphene oxide,...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4188409/ https://www.ncbi.nlm.nih.gov/pubmed/25298756 http://dx.doi.org/10.1186/1556-276X-9-535 |
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author | Rajagopalan, Balasubramaniyan Chung, Jin Suk |
author_facet | Rajagopalan, Balasubramaniyan Chung, Jin Suk |
author_sort | Rajagopalan, Balasubramaniyan |
collection | PubMed |
description | An efficient active material for supercapacitor electrodes is prepared by reacting potassium hydroxide (KOH) with graphene oxide followed by chemical reduction with hydrazine. The electrochemical performance of KOH treated graphene oxide reduced for 24 h (reduced chemically modified graphene oxide, RCMGO-24) exhibits a specific capacitance of 253 F g(-1) at 0.2 A g(-1) in 2 M H(2)SO(4) compared to a value of 141 F g(-1) for graphene oxide reduced for 24 h (RGO-24), and good cyclic stability up to 3,000 cycles. Interestingly, RCMGO-24 demonstrated a higher specific capacitance and excellent cycle stability due to its residual oxygen functional groups that accelerate the faradaic reactions and aid in faster wetting. This non-annealed strategy offers the potential for simple and cost-effective preparation of an active material for a supercapacitor electrode. |
format | Online Article Text |
id | pubmed-4188409 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | Springer |
record_format | MEDLINE/PubMed |
spelling | pubmed-41884092014-10-08 Reduced chemically modified graphene oxide for supercapacitor electrode Rajagopalan, Balasubramaniyan Chung, Jin Suk Nanoscale Res Lett Nano Express An efficient active material for supercapacitor electrodes is prepared by reacting potassium hydroxide (KOH) with graphene oxide followed by chemical reduction with hydrazine. The electrochemical performance of KOH treated graphene oxide reduced for 24 h (reduced chemically modified graphene oxide, RCMGO-24) exhibits a specific capacitance of 253 F g(-1) at 0.2 A g(-1) in 2 M H(2)SO(4) compared to a value of 141 F g(-1) for graphene oxide reduced for 24 h (RGO-24), and good cyclic stability up to 3,000 cycles. Interestingly, RCMGO-24 demonstrated a higher specific capacitance and excellent cycle stability due to its residual oxygen functional groups that accelerate the faradaic reactions and aid in faster wetting. This non-annealed strategy offers the potential for simple and cost-effective preparation of an active material for a supercapacitor electrode. Springer 2014-09-29 /pmc/articles/PMC4188409/ /pubmed/25298756 http://dx.doi.org/10.1186/1556-276X-9-535 Text en Copyright © 2014 Rajagopalan and Chung; licensee Springer. http://creativecommons.org/licenses/by/4.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited. |
spellingShingle | Nano Express Rajagopalan, Balasubramaniyan Chung, Jin Suk Reduced chemically modified graphene oxide for supercapacitor electrode |
title | Reduced chemically modified graphene oxide for supercapacitor electrode |
title_full | Reduced chemically modified graphene oxide for supercapacitor electrode |
title_fullStr | Reduced chemically modified graphene oxide for supercapacitor electrode |
title_full_unstemmed | Reduced chemically modified graphene oxide for supercapacitor electrode |
title_short | Reduced chemically modified graphene oxide for supercapacitor electrode |
title_sort | reduced chemically modified graphene oxide for supercapacitor electrode |
topic | Nano Express |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4188409/ https://www.ncbi.nlm.nih.gov/pubmed/25298756 http://dx.doi.org/10.1186/1556-276X-9-535 |
work_keys_str_mv | AT rajagopalanbalasubramaniyan reducedchemicallymodifiedgrapheneoxideforsupercapacitorelectrode AT chungjinsuk reducedchemicallymodifiedgrapheneoxideforsupercapacitorelectrode |