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Reduced chemically modified graphene oxide for supercapacitor electrode

An efficient active material for supercapacitor electrodes is prepared by reacting potassium hydroxide (KOH) with graphene oxide followed by chemical reduction with hydrazine. The electrochemical performance of KOH treated graphene oxide reduced for 24 h (reduced chemically modified graphene oxide,...

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Detalles Bibliográficos
Autores principales: Rajagopalan, Balasubramaniyan, Chung, Jin Suk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4188409/
https://www.ncbi.nlm.nih.gov/pubmed/25298756
http://dx.doi.org/10.1186/1556-276X-9-535
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author Rajagopalan, Balasubramaniyan
Chung, Jin Suk
author_facet Rajagopalan, Balasubramaniyan
Chung, Jin Suk
author_sort Rajagopalan, Balasubramaniyan
collection PubMed
description An efficient active material for supercapacitor electrodes is prepared by reacting potassium hydroxide (KOH) with graphene oxide followed by chemical reduction with hydrazine. The electrochemical performance of KOH treated graphene oxide reduced for 24 h (reduced chemically modified graphene oxide, RCMGO-24) exhibits a specific capacitance of 253 F g(-1) at 0.2 A g(-1) in 2 M H(2)SO(4) compared to a value of 141 F g(-1) for graphene oxide reduced for 24 h (RGO-24), and good cyclic stability up to 3,000 cycles. Interestingly, RCMGO-24 demonstrated a higher specific capacitance and excellent cycle stability due to its residual oxygen functional groups that accelerate the faradaic reactions and aid in faster wetting. This non-annealed strategy offers the potential for simple and cost-effective preparation of an active material for a supercapacitor electrode.
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spelling pubmed-41884092014-10-08 Reduced chemically modified graphene oxide for supercapacitor electrode Rajagopalan, Balasubramaniyan Chung, Jin Suk Nanoscale Res Lett Nano Express An efficient active material for supercapacitor electrodes is prepared by reacting potassium hydroxide (KOH) with graphene oxide followed by chemical reduction with hydrazine. The electrochemical performance of KOH treated graphene oxide reduced for 24 h (reduced chemically modified graphene oxide, RCMGO-24) exhibits a specific capacitance of 253 F g(-1) at 0.2 A g(-1) in 2 M H(2)SO(4) compared to a value of 141 F g(-1) for graphene oxide reduced for 24 h (RGO-24), and good cyclic stability up to 3,000 cycles. Interestingly, RCMGO-24 demonstrated a higher specific capacitance and excellent cycle stability due to its residual oxygen functional groups that accelerate the faradaic reactions and aid in faster wetting. This non-annealed strategy offers the potential for simple and cost-effective preparation of an active material for a supercapacitor electrode. Springer 2014-09-29 /pmc/articles/PMC4188409/ /pubmed/25298756 http://dx.doi.org/10.1186/1556-276X-9-535 Text en Copyright © 2014 Rajagopalan and Chung; licensee Springer. http://creativecommons.org/licenses/by/4.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.
spellingShingle Nano Express
Rajagopalan, Balasubramaniyan
Chung, Jin Suk
Reduced chemically modified graphene oxide for supercapacitor electrode
title Reduced chemically modified graphene oxide for supercapacitor electrode
title_full Reduced chemically modified graphene oxide for supercapacitor electrode
title_fullStr Reduced chemically modified graphene oxide for supercapacitor electrode
title_full_unstemmed Reduced chemically modified graphene oxide for supercapacitor electrode
title_short Reduced chemically modified graphene oxide for supercapacitor electrode
title_sort reduced chemically modified graphene oxide for supercapacitor electrode
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4188409/
https://www.ncbi.nlm.nih.gov/pubmed/25298756
http://dx.doi.org/10.1186/1556-276X-9-535
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