Cargando…

Lithium ion conductive behavior of TiO(2) nanotube/ionic liquid matrices

A series of TiO(2) nanotube (TNT)/ionic liquid matrices were prepared, and their lithium ion conductive properties were studied. SEM images implied that ionic liquid was dispersed on the whole surface of TNT. Addition of TNT to ionic liquid (1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)am...

Descripción completa

Detalles Bibliográficos
Autores principales: Vedarajan, Raman, Ogawa, Makoto, Matsumi, Noriyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4193959/
https://www.ncbi.nlm.nih.gov/pubmed/25313300
http://dx.doi.org/10.1186/1556-276X-9-539
_version_ 1782339059684737024
author Vedarajan, Raman
Ogawa, Makoto
Matsumi, Noriyoshi
author_facet Vedarajan, Raman
Ogawa, Makoto
Matsumi, Noriyoshi
author_sort Vedarajan, Raman
collection PubMed
description A series of TiO(2) nanotube (TNT)/ionic liquid matrices were prepared, and their lithium ion conductive properties were studied. SEM images implied that ionic liquid was dispersed on the whole surface of TNT. Addition of TNT to ionic liquid (1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide (BMImTFSA)) resulted in significant increase of ionic conductivity. Furthermore, lithium transference number was also largely enhanced due to the interaction of anion with TNT. Vogel-Fulcher-Tammann parameter showed higher carrier ion number for TNT/BMImTFSA in comparison with BMImTFSA.
format Online
Article
Text
id pubmed-4193959
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher Springer
record_format MEDLINE/PubMed
spelling pubmed-41939592014-10-13 Lithium ion conductive behavior of TiO(2) nanotube/ionic liquid matrices Vedarajan, Raman Ogawa, Makoto Matsumi, Noriyoshi Nanoscale Res Lett Nano Express A series of TiO(2) nanotube (TNT)/ionic liquid matrices were prepared, and their lithium ion conductive properties were studied. SEM images implied that ionic liquid was dispersed on the whole surface of TNT. Addition of TNT to ionic liquid (1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide (BMImTFSA)) resulted in significant increase of ionic conductivity. Furthermore, lithium transference number was also largely enhanced due to the interaction of anion with TNT. Vogel-Fulcher-Tammann parameter showed higher carrier ion number for TNT/BMImTFSA in comparison with BMImTFSA. Springer 2014-10-01 /pmc/articles/PMC4193959/ /pubmed/25313300 http://dx.doi.org/10.1186/1556-276X-9-539 Text en Copyright © 2014 Vedarajan et al.; licensee Springer. http://creativecommons.org/licenses/by/4.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.
spellingShingle Nano Express
Vedarajan, Raman
Ogawa, Makoto
Matsumi, Noriyoshi
Lithium ion conductive behavior of TiO(2) nanotube/ionic liquid matrices
title Lithium ion conductive behavior of TiO(2) nanotube/ionic liquid matrices
title_full Lithium ion conductive behavior of TiO(2) nanotube/ionic liquid matrices
title_fullStr Lithium ion conductive behavior of TiO(2) nanotube/ionic liquid matrices
title_full_unstemmed Lithium ion conductive behavior of TiO(2) nanotube/ionic liquid matrices
title_short Lithium ion conductive behavior of TiO(2) nanotube/ionic liquid matrices
title_sort lithium ion conductive behavior of tio(2) nanotube/ionic liquid matrices
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4193959/
https://www.ncbi.nlm.nih.gov/pubmed/25313300
http://dx.doi.org/10.1186/1556-276X-9-539
work_keys_str_mv AT vedarajanraman lithiumionconductivebehavioroftio2nanotubeionicliquidmatrices
AT ogawamakoto lithiumionconductivebehavioroftio2nanotubeionicliquidmatrices
AT matsuminoriyoshi lithiumionconductivebehavioroftio2nanotubeionicliquidmatrices