Photochemical Tyrosine Oxidation in the Structurally Well-Defined α(3)Y Protein: Proton-Coupled Electron Transfer and a Long-Lived Tyrosine Radical

[Image: see text] Tyrosine oxidation–reduction involves proton-coupled electron transfer (PCET) and a reactive radical state. These properties are effectively controlled in enzymes that use tyrosine as a high-potential, one-electron redox cofactor. The α(3)Y model protein contains Y32, which can be...

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Detalles Bibliográficos
Autores principales: Glover, Starla D., Jorge, Christine, Liang, Li, Valentine, Kathleen G., Hammarström, Leif, Tommos, Cecilia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195373/
https://www.ncbi.nlm.nih.gov/pubmed/25121576
http://dx.doi.org/10.1021/ja503348d

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