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Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand

[Image: see text] Tungsten NAr(R) alkylidene complexes have been prepared that contain the electron-withdrawing Ar(R) groups 2,4,6-X(3)C(6)H(2) (Ar(X3), X = Cl, Br), 2,6-Cl(2)-4-CF(3)C(6)H(2) (Ar(Cl2CF3)), and 3,5-(CF(3))(2)C(6)H(3) (Ar((CF3)2)). Reported complexes include W(NAr(R))(2)Cl(2)(dme) (dm...

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Detalles Bibliográficos
Autores principales: Axtell, Jonathan C., Schrock, Richard R., Müller, Peter, Smith, Stacey J., Hoveyda, Amir H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4195510/
https://www.ncbi.nlm.nih.gov/pubmed/25328268
http://dx.doi.org/10.1021/om5006676