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Detection and Monitoring of Toxic Chemical at Ultra Trace Level by Utilizing Doped Nanomaterial
Composite nanoparticles were synthesized by eco-friendly hydrothermal process and characterized by different spectroscopic techniques. All the spectroscopic techniques suggested the synthesis of well crystalline optically active composite nanoparticles with average diameter of ∼30 nm. The synthesize...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Public Library of Science
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4199608/ https://www.ncbi.nlm.nih.gov/pubmed/25329666 http://dx.doi.org/10.1371/journal.pone.0109423 |
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author | Khan, Sher Bahadar Rahman, Mohammed M. Akhtar, Kalsoom Asiri, Abdullah M. |
author_facet | Khan, Sher Bahadar Rahman, Mohammed M. Akhtar, Kalsoom Asiri, Abdullah M. |
author_sort | Khan, Sher Bahadar |
collection | PubMed |
description | Composite nanoparticles were synthesized by eco-friendly hydrothermal process and characterized by different spectroscopic techniques. All the spectroscopic techniques suggested the synthesis of well crystalline optically active composite nanoparticles with average diameter of ∼30 nm. The synthesized nanoparticles were applied for the development of chemical sensor which was fabricated by coating the nanoparticles on silver electrode for the recognition of phthalimide using simple I–V technique. The developed sensor exhibited high sensitivity (1.7361 µA.mM(−1).cm(−2)), lower detection limit (8.0 µM) and long range of detection (77.0 µM to 0.38 M). Further the resistances of composite nanoparticles based sensor was found to be 2.7 MΩ which change from 2.7 to 1.7 with change in phthalimide concentration. The major advantages of the designed sensor over existing sensors are its simple technique, low cost, lower detection limit, high sensitivity and long range of detection. It can detect phthalimide even at trace level and sense over wide range of concentrations. Therefore the composite nanoparticals would be a better choice for the fabrication of phthalimide chemical sensor and would be time and cost substituted implement for environmental safety. |
format | Online Article Text |
id | pubmed-4199608 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | Public Library of Science |
record_format | MEDLINE/PubMed |
spelling | pubmed-41996082014-10-21 Detection and Monitoring of Toxic Chemical at Ultra Trace Level by Utilizing Doped Nanomaterial Khan, Sher Bahadar Rahman, Mohammed M. Akhtar, Kalsoom Asiri, Abdullah M. PLoS One Research Article Composite nanoparticles were synthesized by eco-friendly hydrothermal process and characterized by different spectroscopic techniques. All the spectroscopic techniques suggested the synthesis of well crystalline optically active composite nanoparticles with average diameter of ∼30 nm. The synthesized nanoparticles were applied for the development of chemical sensor which was fabricated by coating the nanoparticles on silver electrode for the recognition of phthalimide using simple I–V technique. The developed sensor exhibited high sensitivity (1.7361 µA.mM(−1).cm(−2)), lower detection limit (8.0 µM) and long range of detection (77.0 µM to 0.38 M). Further the resistances of composite nanoparticles based sensor was found to be 2.7 MΩ which change from 2.7 to 1.7 with change in phthalimide concentration. The major advantages of the designed sensor over existing sensors are its simple technique, low cost, lower detection limit, high sensitivity and long range of detection. It can detect phthalimide even at trace level and sense over wide range of concentrations. Therefore the composite nanoparticals would be a better choice for the fabrication of phthalimide chemical sensor and would be time and cost substituted implement for environmental safety. Public Library of Science 2014-10-16 /pmc/articles/PMC4199608/ /pubmed/25329666 http://dx.doi.org/10.1371/journal.pone.0109423 Text en © 2014 Khan et al http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are properly credited. |
spellingShingle | Research Article Khan, Sher Bahadar Rahman, Mohammed M. Akhtar, Kalsoom Asiri, Abdullah M. Detection and Monitoring of Toxic Chemical at Ultra Trace Level by Utilizing Doped Nanomaterial |
title | Detection and Monitoring of Toxic Chemical at Ultra Trace Level by Utilizing Doped Nanomaterial |
title_full | Detection and Monitoring of Toxic Chemical at Ultra Trace Level by Utilizing Doped Nanomaterial |
title_fullStr | Detection and Monitoring of Toxic Chemical at Ultra Trace Level by Utilizing Doped Nanomaterial |
title_full_unstemmed | Detection and Monitoring of Toxic Chemical at Ultra Trace Level by Utilizing Doped Nanomaterial |
title_short | Detection and Monitoring of Toxic Chemical at Ultra Trace Level by Utilizing Doped Nanomaterial |
title_sort | detection and monitoring of toxic chemical at ultra trace level by utilizing doped nanomaterial |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4199608/ https://www.ncbi.nlm.nih.gov/pubmed/25329666 http://dx.doi.org/10.1371/journal.pone.0109423 |
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