1,2-N-Migration in a Gold-Catalysed Synthesis of Functionalised Indenes by the 1,1-Carboalkoxylation of Ynamides

Unique α-hemiaminal ether gold carbene intermediates were accessed by a gold-catalysed 1,1-carboalkoxylation strategy and evolved through a highly selective 1,2-N-migration. This skeletal rearrangement gave functionalised indenes, and isotopic labelling confirmed the rare C–N bond cleavage of the yn...

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Detalles Bibliográficos
Autores principales: Adcock, Holly V, Langer, Thomas, Davies, Paul W
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4204129/
https://www.ncbi.nlm.nih.gov/pubmed/24828030
http://dx.doi.org/10.1002/chem.201403040

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4204129/
https://www.ncbi.nlm.nih.gov/pubmed/24828030
http://dx.doi.org/10.1002/chem.201403040

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